TERT-BUTYLMAGNESIUM CHLORIDE 叔丁基氯化镁

规格:
CAS: 677-22-5
产品编号: HXYJ0000003519
MDL: MFCD00000465
品牌: Bellen
Chemical Nametert-Butylmagnesium chloride
CAS Number677-22-5
EC Number250-023-7
Beilstein Registry Number3535403
MDL NumberMFCD00000465
PubChem Substance ID87564088
Synonym Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal solution~1MinTHF t-Butylmagnesium Chloride 1.0 M In Tetrahydrofuran tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L) {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {}
Reaxys-RN3911207
Chemical Name Translation叔丁基氯化镁
InChIKeyCQRPUKWAZPZXTO-UHFFFAOYSA-M
LabNetwork Molecule IDLN00163692
InChIInChI=1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q-1;;+2/p-1
Canonical SMILESCC([Mg]Cl)(C)C
GHS Symbol
Signal word Danger
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R14 Reacts violently with water 遇水会猛烈反应
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
    • R17 Spontaneously flammable in air 在空气中能够自燃
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R22 Harmful if swallowed 吞咽有害
    • R34 Causes burns 会导致灼伤
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
      Precautionary statements
      • P201 Obtain special instructions before use. 使用前获取专门指示。
      • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P222 Do not allow contact with air. 不要与空气接触。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
      • P231+P232
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241+P242+P243
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331+P310
      • P303+P361+P353
      • P303+P361+P353+P310+P363
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P310
      • P308+P313
      • P335+P334
      • P370+P378
      • P402+P404
      • P403+P233
      • P405 Store locked up. 上锁保管。
      • P422 Store contents under… 存储目录在…之下。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
        • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
        • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
        • H302 Harmful if swallowed 吞食有害
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
        • H351 Suspected of causing cancer 怀疑致癌
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes 4.3 F+,C,F F,C
          Packing GroupI
          UN Number 3399
          Storage condition -20°C {LY} -20°C Air & Moisture Sensitive {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°
          Hazard Class4.3/3
          Restrict 危险品
        • Reagent used in an Fe(acac)3-catalyzed cross-coupling with chloroenynols
        • {ALD} Beilstein: 4,665
          • 677-22-5 HXYJ0000003519 TERT-BUTYLMAGNESIUM CHLORIDE 叔丁基氯化镁

          化学属性

          Mol. FormulaC4H9ClMg
          Mol. Weight116.87
          Density0.931
          TSCANo
          Flash Point34 °F
          Stability对空气和湿度敏感，密封充氩保存
          Boiling Point77-79

          *以上化合物性质及应用等信息仅供参考