Allyltributyltin 烯丙基三丁基锡

规格:
CAS: 24850-33-7
产品编号: HXYJ0000003635
MDL: MFCD00010346
品牌: Bellen
Chemical NameAllyltributylstannane
CAS Number24850-33-7
Alfabeta NameALLYLTRIBUTYLSTANNANE
MDL NumberMFCD00010346
PubChem Substance ID24856436
EC Number246-494-3
Beilstein Registry Number3588340
Synonym 烯丙基三丁基锡 Allyltri-n-butyltin Allyltributyltin Tributyl-2-propenylstannane
Chemical Name Translation烯丙基三丁基锡
GHS Symbol
Warnings IRRITANT
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H301 Toxic if swallowed 吞食有毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Precautionary statements
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P301+P310
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P305+P351+P338
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P301+P310+P330
    • P302+P352+P312
      Signal word Danger
      Packing GroupIII
      UN Number UN2788
      Risk Statements
      • R25 Toxic if swallowed 吞咽有毒
      • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
      • R21 Harmful in contact with skin 与皮肤接触有害
      • R48/23/25
      • R50/53
        Safety Statements
        • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
          Storage condition 对空气敏感 Air Sensitive
          Hazard Codes T,N
        • {ALF} Lewis acid-catalyzed stereoselective addition to aldehydes gives homoallylic alcohols: Chem. Lett., 919 (1979); Tetrahedron Lett., 25, 265, 1879 (1984); Synlett, 1694 (2002). For chemoselective allylation of aldehydes in the presence of ketones, see: Tetrahedron Lett., 36, 3723 (1995). In the presence of TI(O-i-Pr)4 and BINOL, enantioselective allylation of ketones can be accomplished with high ee: Tetrahedron: Asym., 11, 4163 (2000).
        • {ALF} Widely used nucleophilic, non-basic allylating agent.
        • {ALF} Couples with primary or secondary alkyl halides under free-radical conditions: J. Am. Chem. Soc., 104, 5829 (1982); Bull. Chem. Soc. Jpn., 56, 24801 (1983).
        • {ALF} Similarly, homoallylamines are formed from aldimines with TiCl4 or BF3 etherate: J. Org. Chem., 50, 146 (1985). For allylation of quinones, see p-Benzoquinone, A13162.
          • 24850-33-7 HXYJ0000003635 Allyltributyltin 烯丙基三丁基锡

          化学属性

          Mol. FormulaC15H32Sn
          Mol. Weight331
          Refractive indexn20/D 1.486(lit.)
          Boiling Point88-92 °C/0.2 mmHg(lit.)
          Density1.068 g/mL at 25 °C(lit.)
          Flash Point103°(217°F)
          TSCANo
          Stability对空气敏感

          *以上化合物性质及应用等信息仅供参考