| Chemical Name | Hexamethylditin |
|---|
| Synonym |
Distannane, hexamethyl-
HEXAMETHYLDISTANNANE
HEXAMETHYLDITIN
HEXAMETHYLDITIN(IV)
Hexamethylditin
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| CAS Number | 661-69-8 |
|---|
| PubChem Substance ID | 6327618 |
|---|
| EC Number | 211-549-2 |
|---|
| Beilstein Registry Number | 4(4)4346 |
|---|
| MDL Number | MFCD00008277 |
|---|
| Reaxys-RN | 3600327 |
|---|
| Chemical Name Translation | 六甲基二锡 |
|---|
| Wiswesser Line Notation | 1-SN-1&1&-SN-1&1&1 |
|---|
| InChIKey | CCRMAATUKBYMPA-UHFFFAOYSA-N |
|---|
| LabNetwork Molecule ID | LN00001309 |
|---|
| InChI | InChI=1S/6CH3.2Sn/h6*1H3;; |
|---|
GHS Symbol
| WGK Germany | 2 |
|---|
| Hazard statements | |
|---|
- H300+H310+H330
- H330 Fatal if inhaled 吸入致命
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H310 Fatal in contact with skin 皮肤接触致命
- H300 Fatal if swallowed 吞食致命
|
| Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes |
T+,N |
| RTECS | WH8280000 |
|---|
| Precautionary statements | |
|---|
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P304+P340+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P302+P350
- P403+P233
- P302+P352+P310+P361+P364
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
|
| Signal word |
Danger |
| UN Number |
3146 |
| Risk Statements | |
|---|
- R24 Toxic in contact with skin 与皮肤接触有毒
- R28 Very toxic if swallowed 吞咽极毒
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
- R50/53
|
| Safety Statements | |
|---|
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S27/28
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
|
| Storage condition |
Air Sensitive |
| Packing Group | II |
|---|
| Hazard Class | 6.1 |
|---|
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 7690 ug/kg
TOXIC EFFECTS :
Behavioral - tremor
Behavioral - excitement
Behavioral - ataxia
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: OTS0555199
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Administration onto the skin
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 53800 ug/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: OTS0555183
| Restrict |
剧毒 |
{SA}
1. Tetrahedron Lett. 47 , 8973, (2006)
{SA}
2. Tetrahedron Lett. 47 , 8607, (2006)
{SA}
Beil. 4 ,IV,4346
{SA}
Fieser 6 ,273 / Fieser 13 ,142 / Fieser 17 ,143
{SA}
Corp MSDS 1 (1), 1851:C / FT-IR 2 (3), 4477:C / FT-NMR 1 (3), 737:B / RegBook 1 (2), 3043:C / Sax 6 , 1521 / Structure Index 1 , 481:B:6 / Vapor Phase 3 , 1682:A
{uni_hamburg} Short: II/25D
Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms
Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
Editor: Kuchitsu, K.
Source: Landolt-Börnstein, New Series
Volume: II/25D
Year: 2003
Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
ISBN: 3-540-42860-7
ISBN: 978-3-540-42860-2
Internet Resource: DOI:10.1007/b75952
RefComment: VIII, 569 pages. Hardcover
RefComment: Written for scientists and researchers in the fields of chemistry and physics
Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
{uni_hamburg} Short: III/35C4
Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and
