Copper(II) trifluoromethanesulfonate 三氟甲烷磺酸酮

规格:
CAS: 34946-82-2
产品编号: HXYJ0000016212
MDL: MFCD00077492
品牌: Bellen
Chemical NameCopper(II) trifluoromethanesulfonate
Synonym Copper(II) trifluoromethanesulfonate {LY} Copper(II) trifluoromethanesulfonate {} {LY} Copper(II) trifluoromethanesulfonate {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number252-300-8
Beilstein Registry Number4028198
PubChem Substance ID87577063
Reaxys-RN4028198
Chemical Name Translation三氟甲烷磺酸酮
LabNetwork Molecule IDLN00224893
InChIKeyHRQFBGFAQQDQJD-UHFFFAOYSA-N
CAS Number34946-82-2
MDL NumberMFCD00077492
InChIInChI=1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
Canonical SMILESO=S([O-])(C(F)(F)F)=O.[Cu+2]
GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Packing GroupII
    UN Number 1759 3261
    Risk Statements
    • R34 Causes burns 会导致灼伤
      Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
      WGK Germany3
      Precautionary statements
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P301+P330+P331+P310
      • P303+P361+P353+P310+P363
      • P304+P340
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P310
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
          Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
          Signal word Danger
          Hazard Codes 8 C
          Hazard Class8
        • 有效催化把三甲基甲硅烷氰基添加到羰基化合物。
        • {ALF} Friedel-Crafts alkylation and acylation reactions of aromatics are also catalyzed: Tetrahedron, 57, 241 (2001).
        • {ALF} Widely used to generate carbenoid species from ɑ-diazo esters and ketones, via in situ reduction to the Cu(I) species: J. Am. Chem. Soc., 95, 3300 (1973). Preferred reagent for intramolecular cyclization of various diazo ketones: J. Org. Chem., 49, 11496 (1984). Also promotes the reaction between diazo esters and imines to give aziridines: J. Chem. Soc., Chem. Commun., 1 (1995).
        • {ALF} Catalyzes syn-selective aldol condensation of (Z)-silyl enol ethers with aldehydes: Chem. Lett., 959 (1997).
        • {ALF} Mild Lewis acid:
        • {ALF} Used catalytically, promotes dehydration of alcohols and diols to alkenes at ambient temperatures: Helv. Chim. Acta, 70, 607 (1987).
        • {ALF} For a brief feature on uses of the reagent in synthesis, see: Synlett, 1044 (2005).
          • 34946-82-2 HXYJ0000016212 Copper(II) trifluoromethanesulfonate 三氟甲烷磺酸酮

          化学属性

          Melting Point>300°C
          TSCANo
          Density1.422
          Mol. FormulaC2CuF6O6S2
          Appearance light green solid white to light green solid
          Mol. Weight361.68
          Stabilityhygroscopic

          *以上化合物性质及应用等信息仅供参考