三甲基膦 三甲基膦

规格:
CAS: 594-09-2
产品编号: HXYJ0000016232
MDL: MFCD00008510
品牌: Bellen
Chemical NameTrimethylphosphine
Synonym trimethylphosphine 三甲基磷 Trimethylphosphine solution TRIMETHYLPHOSPHINE, 1.0M SOLUTION IN TET RAHYDROFURAN Methyl phosphine TRIMETHYLPHOSPHINE, 1.0M SOLUTION IN TOL UENE TRIMETHYLPHOSPHINE SOLUTION, ~1 M IN THF trimethylphosphane TRIMETHYLPHOSPHINE SOLUTION, ~1 M IN TOL UENE 三甲基膦 Trimethylphosphineminampouled trimethyl-phosphine 2甲基磷 TrimethylphosphineSureSealbottlecolorlessliquid 三甲膦 PHOSPHORUS TRIMETHYL PMe3 Trimethylphosphorus TRIMETHYLPHOSPHINE Trimethylphosphine,min.99% Trimethylphosphine,99% Trimethylphosphine,min.99%(Sure/Sealbottle) Trimethylphosphorus PMe3 甲膦 Trimethylphosphine,min. 99% Trimethyl-phosphane 三甲基膦 溶液 Phosphine, trimethyl- (CH3)3P
PubChem Substance ID68983
Beilstein Registry Number969138
EC Number209-823-1
Chemical Name Translation三甲基膦
InChIKeyYWWDBCBWQNCYNR-UHFFFAOYSA-N
Reaxys-RN969138
MDL NumberMFCD00008510
CAS Number594-09-2
LabNetwork Molecule IDLN00162792
InChIInChI=1S/C3H9P/c1-4(2)3/h1-3H3
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H351 Suspected of causing cancer 怀疑致癌
  • H302 Harmful if swallowed 吞食有害
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241+P242+P243
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
    • P301+P312+P330
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P370+P378
    • P403+P235
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S33 Take precautionary measures against static discharges 对静电采取预防措施；
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
      • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        Packing GroupII
        UN Number 1993 UN 1993 3/PG 2 UN2845
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R17 Spontaneously flammable in air 在空气中能够自燃
        • R19 May form explosive peroxides 可能生成易爆的过氧化物质
        • R34 Causes burns 会导致灼伤
        • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R38 Irritating to skin 刺激皮肤
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
        • R48/20
        • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
        • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
        • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
          Storage condition 对空气和湿度敏感，密封保存。 Air & Moisture Sensitive 储存温度2-8℃ 2-8°C
          Hazard Codes 3 F,Xn F;Xi
          Hazard Class3
          Restrict 危险品
        • 富电子膦配体,可用于偶联反应。
        • {uni_hamburg} Short: II/24A
        • {ALD} 4,IV,3420 / Beil. 4,580
        • {uni_hamburg} Short: II/19a
          • 594-09-2 HXYJ0000016232 三甲基膦 三甲基膦

          化学属性

          Refractive indexn20/D 1.428(lit.)
          Vapor Pressure7.24 psi ( 20 °C)
          TSCANo
          Mol. Formula(CH3)3P
          Mol. Weight76
          Density0.872
          Flash Point-22°F
          Appearance colorless liq.
          Stabilityair sensitive
          Boiling Point38-40°C
          Melting Point-85°C

          *以上化合物性质及应用等信息仅供参考