| Chemical Name | Tetramethylgermanium |
|---|
| Synonym |
四甲基锗
(CH3)4Ge
GERMANIUM TETRAMETHYL
TETRAMETHYLGERMANIUM
tetramethylgermane
Tetramethylgermanium,98%
TL 81
TETRAMETHYLGERMANE
tetramethyl-germane
tetramethyl germanium
germane, tetramethyl-
TETRAMETHYLGERMANIUM SOLUTION, ~2.9 M IN THF
Tetramethylgermanium
tetramethylgermanium
Tetramethylgermane,99%
Tetramethylgermanium solution
tl81
tetramethyl-germaniu
Tetralmethylgermanium |
| PubChem Substance ID | 70079 |
|---|
| EC Number | 212-745-0 |
|---|
| Reaxys-RN | 3660066 |
|---|
| Chemical Name Translation | 四甲基锗 |
|---|
| InChIKey | ZRLCXMPFXYVHGS-UHFFFAOYSA-N |
|---|
| Beilstein Registry Number | 3660066 |
|---|
| LabNetwork Molecule ID | LN01247179 |
|---|
| InChI | InChI=1S/C4H12Ge/c1-5(2,3)4/h1-4H3 |
|---|
| MDL Number | MFCD00014843 |
|---|
| CAS Number | 865-52-1 |
|---|
GHS Symbol
| WGK Germany | 3 |
|---|
| Hazard Codes |
F,Xn |
| Hazard statements | |
|---|
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
|
| Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| RTECS | LY5345000 |
|---|
| Precautionary statements | |
|---|
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P317
- P302+P352
- P303+P361+P353
- P304+P312
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P317
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P337+P313
- P337+P317
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
| Signal word |
Danger
{} {} {} {} {} {} {} {} {TCI} |
| UN Number |
UN 1993 3/PG 2
UN1993
1993 |
| Storage condition |
0-10
Flammables area
0-10°C |
| Risk Statements | |
|---|
- R11 Highly flammable 非常易燃
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R36 Irritating to eyes 刺激眼睛
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
|
| Safety Statements | |
|---|
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
|
| Packing Group | II |
|---|
| Hazard Class | 3 |
|---|
TYPE OF TEST : LC - Lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : >2500 mg/m3/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research
and Development, Progress Report. Volume(issue)/page/year:
NDCrc-132,Mar,1942
{uni_hamburg} Short: II/25C
Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms
Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
Editor: Kuchitsu, K.
Source: Landolt-Börnstein, New Series
Volume: II/25C
Year: 2001
Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
ISBN: 3-540-66774-1
ISBN: 978-3-540-66774-2
Internet Resource: DOI:10.1007/b71431
RefComment: VIII, 481 pages. Hardcover
Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
{uni_hamburg} Short: III/35C4
Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
Author: Gupta, R.R.; Platzer, N.
Editor: Gupta, R.R.; Lechner, M.D.
Source: Landolt-Börnstein, New Series
Volume: III/35C4
Year: 2001
Keyword: Hydrogen 1; Nuclear Magnetic Resonance
ISBN: 3-540-41059-7
ISBN: 978-3-540-41059-1
Internet Resource: DOI:10.1007/b76570
RefComment: VII, 299 pages. With CD-ROM. Hardcover
Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling consta
