三（二甲氨基）膦 三（二甲氨基）膦

规格:
CAS: 1608-26-0
产品编号: HXYJ0000017327
MDL: MFCD00008301
品牌: Bellen
Chemical NameHexamethylphosphorous Triamide
Synonym N,N,N',N',N'',N''-Hexamethylphosphinetriamine {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosp
EC Number216-534-4
Beilstein Registry Number4(4)274
PubChem Substance ID87577088
Reaxys-RN906778
Chemical Name Translation三(二甲胺基)膦
LabNetwork Molecule IDLN00226609
MDL NumberMFCD00008301
CAS Number1608-26-0
InChIInChI=1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
Canonical SMILESCN(C)P(N(C)C)N(C)C
GHS Symbol
TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 212,193,1989

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Kidney
DOSE/DURATION           : 2500 ug/L
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   38,418,1978

Signal word Danger Warning
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
    Risk Statements
    • R45 May cause cancer 可能致癌
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R46 May cause inheritable genetic damage 可能引起遗传基因损害
    • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
    • R10 Flammable 易燃
      Precautionary statements
      • P201 Obtain special instructions before use. 使用前获取专门指示。
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241+P242+P243
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P312+P330
      • P302+P352+P312+P362+P364
      • P303+P361+P353
      • P304+P340+P312
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P308+P313
      • P332+P313
      • P337+P313
      • P370+P378
      • P403+P235
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H340 May cause genetic defects 可能导致遗传性缺陷
        • H350 May cause cancer 可能致癌
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
          RTECSTH3390000
          Packing GroupIII
          UN Number 1993 UN 1993 3/PG 3 UN1993
          Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C Air Sensitive Store at RT. {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {L
          Hazard Codes T T,Xi,Xn Xn
          Hazard Class3
        • Reagent combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; hydroxyl group activation; dehydrations.
        • {ALF} Has also been used for a variety of other reductions including that of ozonolysis intermediates: Helv. Chim. Acta, 50, 2387 (1967), and of primary alkyl nitro compounds to nitriles: Synthesis, 36 (1979). Bromohydrins can be converted to alkenes, by reductive elimination from their triflate esters: J. Am. Chem. Soc., 102, 1433 (1980):
        • {ALF} Reacts with BrCCl3 to give dichloromethylenephosphorane Cl2C=PPh3, which undergoes Wittig reaction with aldehydes to give 1,1-dichloroalkenes, giving better results than the CCl4/PPh3 combination: Tetrahedron Lett., 1237, 1239 (1977); Synthesis, 554 (1980). Similarly, with Br2CF2, the CF2 group can be transferred to both aldehydes and ketones: J. Fluorine Chem., 1, 123 (1971); Synth. Commun., 3, 197 (1973).
        • {ALF} Reduces aromatic aldehydes to symmetrical epoxides in good yield: J. Am. Chem. Soc., 85, 1884 (1963). Both cis- and trans-isomers are formed. For list of examples, see: Org. Synth. Coll., 5, 358 (1973). Under suitable conditions, reaction of the intermediate with a second aldehyde can lead to mixed deoxybenzoins or diaryl enamines: Synthesis, 225 (1991).
        • {TRC} Ryu, H., et al.: J. Mat. Sci., 41, 8265 (2006),
        • {uni_hamburg} Short: II/2
        • {uni_hamburg} Short: II/25D
          • 1608-26-0 HXYJ0000017327 三（二甲氨基）膦 三（二甲氨基）膦

          化学属性

          Refractive index1.4640 to 1.4670
          TSCAYes
          Melting Point-44°C
          Solubility起反应
          Mol. FormulaC6H18N3P
          Mol. Weight163.21
          Density0.898
          Flash Point27°C
          Appearance yellow liq.
          Stabilityair sensitive, moisture sensitive
          Boiling Point160.3°C at 760 mmHg

          *以上化合物性质及应用等信息仅供参考