三(五氟苯基)硼

规格:
CAS: 1109-15-5
产品编号: HXYJ0000017958
MDL: MFCD00269813
品牌: Bellen
Chemical NameTris(Pentafluorophenyl)Borane
PubChem Substance ID87558752
Reaxys-RN2931347
Merck Number9755
Synonym Tris(perfluorophenyl)borane {LY} Tris(perfluorophenyl)borane {} {LY} Tris(perfluorophenyl)borane {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pe
Beilstein Registry Number2931347
EC Number250-023-7
Chemical Name Translation三(五氟苯基)硼烷
LabNetwork Molecule IDLN00145630
InChIInChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
MDL NumberMFCD00269813
CAS Number1109-15-5
Canonical SMILESFC1=C(F)C(F)=C(F)C(F)=C1B(C2=C(F)C(F)=C(F)C(F)=C2F)C3=C(F)C(F)=C(F)C(F)=C3F
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Hazard Codes T Xi Xi,T,N,Xn,F
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Signal word Warning
      Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen <0°C <;0 Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {}
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
      • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
      • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
        UN Number UN 1268 3/PG 2 UN2811
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Packing GroupIII
          Hazard Class6.1
        • A useful component of Ziegler-Nattametallocene catalyst for polyolefins.
        • {ALFA} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between -78o and ambient. Also effective for Michael additions of silyl enol ethers with enones: Synlett, 577 (1993). Low-temperature condensation of ester enol silanes with imines provides a route to &#223;-amino esters: Synlett, 963 (1994). Superior catalyst to TBAF for O-silylation with trialkyl or triaryl silanes. Alcohols and phenols are silylated using 2-8 mol% catalyst, with secondary and tertiary alcohols reacting faster than primary: J. Org. Chem., 64, 4887 (1999). Effective catalyst for reduction with Triethyl&#x00AD;silane, A10320, of alcohols and ethers to alkyls: Tetrahedron Lett., 40, 8919 (1999). Catalyst for highly efficient hydrosilylation of olefins with silanes R3SiH: J. Org. Chem., 67, 1936 (2002).
        • {ALF} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between
        • {ALFA} Catalyst for regioselective rearrangement of epoxides to carbonyl compounds: Synlett., 721 (1995), and efficient cleavage of epoxides with allyl and propargyl alcohols, amines and thiols: Tetrahedron Lett., 43, 3801 (2002).
        • {SA} J. Am. Chem. Soc. 129 , 1880, (2007) 摘要
        • {SA} Merck 14 ,9755
          • 1109-15-5 HXYJ0000017958 三(五氟苯基)硼

          化学属性

          Melting Point126-131°C
          TSCAYes
          Density0.73
          Refractive indexn20/D 1.41
          Flash Point7 °C
          Mol. FormulaC18BF15
          Mol. Weight511.98
          Appearance off-white pwdr.
          Stabilitymoisture sensitive
          Boiling Point327.3±42.0 °C at 760 mmHg

          *以上化合物性质及应用等信息仅供参考