三叔丁氧基氢化铝锂1.1M THF

规格:
CAS: 17476-04-9
产品编号: HXYJ0000019089
MDL: MFCD00011532
品牌: Bellen
Chemical NameLithium Tri-t-Butoxyaluminohydride
Synonym LITHIUM ALUMINIUM TRI-TERT-BUTOXYHYDRIDE LITHIUM HYDRIDOTRIS(TERT-BUTOXY)ALUMINATE LITHIUM TRI-TERT-BUTOXYALUMINOHYDRIDE LITHIUM TRI-TERT-BUTOXYALUMINOHYDRIDE, 1 .0M SOLUTION IN TETRAHYDROFURAN Lithium aluminum-tri-tert-butoxyhydride Lithium tri-tert-butoxyaluminohydride, 1.1M solution in THF aluminium lithium tri-tert-butoxide hydride lithium,(beta-4)-aluminate(1-hydrotris(2-methyl-2-propanolato)- lithiumhydrotris(2-methyl-2-propenolato)aluminate tri-tert-butoxyhydruredelithium-aluminium 三叔丁氧基氢化铝锂 三叔丁氧基氢化铝锂 溶液 三叔丁氧基氢化锂铝
MDL NumberMFCD00011532
Beilstein Registry Number5796791
EC Number241-490-8
CAS Number17476-04-9
PubChem Substance ID87572110
Reaxys-RN5796791
Chemical Name Translation三叔丁氧基氢化铝锂
InChIKeyIVEFUNPTURRNIK-UHFFFAOYSA-N
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 32 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00620

RTECSOJ5585000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P335+P334
  • P370+P378
  • P402+P404
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Hazard statements
    • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
    • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
    • H302 Harmful if swallowed 吞食有害
    • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
    • H351 Suspected of causing cancer 怀疑致癌
      WGK Germany1
      Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
      Signal word Danger
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S30 Never add water to this product 切勿将水加入该产品中；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
        Packing GroupI
        UN Number 1409 3399
        Risk Statements
        • R10 Flammable 易燃
        • R11 Highly flammable 非常易燃
        • R14 Reacts violently with water 遇水会猛烈反应
        • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
        • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
        • R19 May form explosive peroxides 可能生成易爆的过氧化物质
        • R34 Causes burns 会导致灼伤
        • R35 Causes severe burns 会导致严重灼伤
        • R37 Irritating to respiratory system 刺激呼吸道
        • R60 May impair fertility 可能降低生殖能力
        • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
          Storage condition Moisture Sensitive 2-8°C
          Hazard Codes 4.3 F,C
          Hazard Class4.3/3
        • ⑴. 在280℃真空升华，本品可溶于乙二醇二甲醚、二甘醇二甲醚和四氢呋喃，微溶于乙醚。在干燥的空气中稳定，在潮湿空气中吸潮水解。和水剧烈反应。
        • ⑵. 是比氢化铝锉温和的高选择性还原剂，很近似于氢化硼钠。在0℃的乙醚或二甘醇二甲醚中可还原醛、酮、酸氯，不还原脂肪酸酯和腈，但可还原脂肪酸和脂环酸的苯醋。还原四氢呋喃(开环)。广泛用于甾体酮的还原
        • 本品是一种温和的高选择性还原剂，在0℃的乙醚或二甘醇二甲醚中可还原酮，醛和酰氯，不还原脂肪酸酯和腈，但可还原脂肪酸和脂环酸的苯酯，还原四氢呋喃(开环)。
        • 在医药、香料、农药、染料以及其他精细有机合成中用作还原剂。广泛用于甾体酮的
        • {ALD} Beilstein: 1,IV,1612
          • 17476-04-9 HXYJ0000019089 三叔丁氧基氢化铝锂1.1M THF

          化学属性

          Mol. FormulaC12H28AlLiO3
          Mol. Weight254.27
          Melting Point300-319
          Density0.904
          Flash Point-21°C(lit.)
          TSCAYes
          Danger-Level甲类

          *以上化合物性质及应用等信息仅供参考