| Chemical Name | Tetramethyltin |
|---|
| Synonym |
{uni_hamburg}
tetramethyl-stannane
Stannane, tetramethyl-
Tetramethylstannane
tin, tetramethyl-
Tetramethylstannane-
TETRAMETHYLTIN
tetramethyl-stannan
TETRAMETHYLTIN, 99+%
Zinntetramethyl
Tetramethylcin
四甲基锡
(CH3)4Sn
tatramethyl stannane
stannane, tetramethyl-
tetramethyl-ti
TIN TETRAMETHYL
tetramethyl stannane
Tin, tetramethyl-
Tetramethyl tin
Tetramethyltin,98%
Tetramethylzinn
tetramethylstannane
四甲錫
四甲锡
TETRAMETHYLSTANNANE
tetramethyltin
TETRAMETHYLTIN(IV) |
| PubChem Substance ID | 11661 |
|---|
| EC Number | 209-833-6 |
|---|
| Beilstein Registry Number | 4,631 |
|---|
| Reaxys-RN | 3647887 |
|---|
| Chemical Name Translation | 四甲基锡 |
|---|
| Wiswesser Line Notation | 1-SN-1&1&1 |
|---|
| LabNetwork Molecule ID | LN02129244 |
|---|
| MDL Number | MFCD00008278 |
|---|
| CAS Number | 594-27-4 |
|---|
| InChI | InChI=1S/4CH3.Sn/h4*1H3; |
|---|
GHS Symbol
| WGK Germany | 3 |
|---|
| Hazard statements | |
|---|
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H330 Fatal if inhaled 吸入致命
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H310 Fatal in contact with skin 皮肤接触致命
- H300 Fatal if swallowed 吞食致命
|
| Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes |
T+,N
T+;N |
| RTECS | WH8630000 |
|---|
| Precautionary statements | |
|---|
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P304+P340+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P403+P233
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P303+P361+P353
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
|
| Signal word |
Danger
Warning |
| UN Number |
UN 3384 6.1/PG 1
UN1992
3384
UN3384 |
| Risk Statements | |
|---|
- R11 Highly flammable 非常易燃
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
- R50/53
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
| Safety Statements | |
|---|
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S4 Keep away from living quarters 远离生活区；
- S27/28
|
| Packing Group | I |
|---|
| Hazard Class | 6.1/3 |
|---|
| Storage condition |
2-8°C |
TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 2550 mg/m3/10M
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation
Behavioral - convulsions or effect on seizure threshold
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research
and Development, Progress Report. Volume(issue)/page/year:
NDCrc-132,FEB1942
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 18 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1245,1986
| Restrict |
剧毒 |
{SA}
Beil. 4 ,IV,4307
{SA}
FT-IR 1 (2), 1143:B / FT-NMR 1 (3), 737:A
{uni_hamburg} Short: II/25C
Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms
Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
Editor: Kuchitsu, K.
Source: Landolt-Börnstein, New Series
Volume: II/25C
Year: 2001
Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
ISBN: 3-540-66774-1
ISBN: 978-3-540-66774-2
Internet Resource: DOI:10.1007/b71431
RefComment: VIII, 481 pages. Hardcover
Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
{uni_hamburg} Short: III/35C4
Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
Author: Gupta, R.R.; Platzer, N.
Editor: Gupta, R.R.; Lechner, M.D.
Source: Landolt-Börnstein, New Series
Volume: III/35C4
Year: 2001
Keyword: Hydrogen 1; Nuclear Magnetic Resonance
ISBN: 3-540-41059-7
ISBN: 978-3-540-41059-1
Internet Resource: DOI:10.1007/b76570
RefComment: VII, 299 pages. With CD-ROM. Hardcover
Abstract: This volume provides a comprehen
