Trimethylphenylammonium tribromide 苯基三甲基三溴化铵

规格: 97%
CAS: 4207-56-1
产品编号: H62675
MDL: MFCD00011789
品牌: INFI
Chemical NamePhenyltrimethylammonium tribromide
Synonym Ammonium, trimethylphenyl-, (tribromide) Benzenaminium, N,N,N-trimethyl-, (tribromide) PHENYLTRIMETHYLAMMONIUM BROMIDE DIBROMIDE PHENYLTRIMETHYLAMMONIUM TRIBROMIDE Phenyltrimethylammonium bromide dibromide Phenyltrimethylammonium perbromide Phenyltrimethylammonium tribomide TRIMETHYLPHENYLAMMONIUM TRIBROMIDE Trimethylphenylammonium tribromide n,n,n-trimethyl-benzenaminiu(tribromide) n,n,n-trimethylanilinium tribromide 苯基三甲基三溴化铵 苯基三甲铵三溴盐
CAS Number4207-56-1
EC Number224-127-8
Beilstein Registry Number3919459
MDL NumberMFCD00011789
PubChem Substance ID87575045
Reaxys-RN3919459
Chemical Name Translation苯基三甲基三溴化铵
InChIKeyPRXNKYBFWAWBNZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00191249
InChIInChI=1S/C9H14N.Br3/c1-10(2,3)9-7-5-4-6-8-9;1-3-2/h4-8H,1-3H3;/q+1;-1
GHS Symbol
Signal word Danger
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
    Risk Statements
    • R34 Causes burns 会导致灼伤
    • R37 Irritating to respiratory system 刺激呼吸道
      Precautionary statements
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P301+P330+P331+P310
      • P303+P361+P353+P310+P363
      • P304+P340
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P310
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
          Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
          Packing GroupII
          UN Number 1759 3261 UN 3261 8/PG 2
          Storage condition 0-10 避光保存 Refrigerator 0-10°C Hygroscopic
          Hazard Codes 8 C
          Hazard Class8
        • 溴化试剂,用于在1,2-位把溴增加到α,β-不饱和化合物的双键上。
        • {ALF} Reagent for the selective ɑ-bromination of acetals with good stability and solubility in organic solvents such as THF: Tetrahedron Lett., 24 (1959); Bull. Soc. Chim. Fr., 1822 (1961); 90 (1962). For example of use in a one-pot ɑ-bromoacetalization of carbonyl com
        • {ALF} For example of selective ɑ-monobromination of ketones, see: Org. Synth. Coll., 6, 175 (1988). Silyl enol ethers are also ɑ-brominated with this reagent to give ɑ-bromo enones: Synlett, 651 (1994).
        • {uni_hamburg} Short: EINECS
        • {ALF} Tosylhydrazones have been oxidized to N-alkenyl-N'-tosyldiazenes: J. Org. Chem., 39, 826 (1974).
        • {ALF} Reagent for the selective ɑ-bromination of acetals with good stability and solubility in organic solvents such as THF: Tetrahedron Lett., 24 (1959); Bull. Soc. Chim. Fr., 1822 (1961); 90 (1962). For example of use in a one-pot ɑ-bromoacetalization of carbonyl compounds in high yields, see: Synthesis, 309 (1982).
        • {uni_hamburg} Short: II/27B
        • {ALD} Beilstein:12,159
        • {ALF} Catalyses the aziridination of alkenes by Chloramine-T trihydrate, A12044: J. Am. Chem. Soc., 120, 6844 (1998).
        • 4207-56-1 H62675 Trimethylphenylammonium tribromide	苯基三甲基三溴化铵

          化学属性

          Mol. FormulaC6H5N(CH3)3Br
          Mol. Weight376
          Density1.443
          Melting Point110-115
          TSCAYes
          Solubility不溶
          Stability对光敏感