Bis(cyclopentadienyl)zirconium dichloride 二氯二茂锆

规格: 98%
CAS: 1291-32-3
产品编号: H76122
MDL: MFCD00003726
品牌: INFI
Chemical NameBis(cyclopentadienyl)zirconium dichloride
Synonym Bis(cyclopentadienyl)zirconium(IV) dichloride
CAS Number1291-32-3
EC Number215-066-8
Beilstein Registry Number2384789
MDL NumberMFCD00003726
PubChem Substance ID87577925
Chemical Name Translation二氯二茂锆
Wiswesser Line NotationL50J 0-ZR-GG- 0L50J
LabNetwork Molecule IDLN01746727
Canonical SMILES[][Zr](Cl)(Cl)[].c1cccc1.c2cccc2
IUPAC Namebis(cyclopenta-1,3-diene);dichlorozirconium(2+)
  • 用于合成许多早期过渡金属络合物和有机金属化合物
  • {PUB} Crystallography Open Database (COD)|PubChem --- Carbon Monoxide-Induced Dinitrogen Cleavage with Group 4 Metallocenes: Reaction Scope and Coupling to N-H Bond Formation and CO Deoxygenation --- https://pubmed.ncbi.nlm.nih.gov/20662528
  • {PUB} Crystallography Open Database (COD)|PubChem --- Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene-Phosphinoaryloxide Complexes --- https://pubmed.ncbi.nlm.nih.gov/21958011
  • {ALF} For reaction of alkene-zirconocene complexes with cyclic enol ethers, see: Angew. Chem. Int. Ed., 43, 3932 (2004).
  • {PUB} PubChem --- Carboxylation of an ansa-Zirconocene Dinitrogen Complex: Regiospecific Hydrazine Synthesis from N2 and CO2 --- https://pubmed.ncbi.nlm.nih.gov/18327948
  • {PUB} PubChem --- Developments of Chiral Metallocenes as Polymerization Catalysts --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147621
  • {PUB} PubChem --- Enantioselective Route from Carbohydrates to Cyclooctane Polyols --- https://pubmed.ncbi.nlm.nih.gov/15673277
  • {PUB} PubChem --- Formal total synthesis of (+/-)-estrone and zirconocene-promoted cyclization of 2-fluoro-1,7-octadienes and ru-catalyzed ring closing metathesis --- https://pubmed.ncbi.nlm.nih.gov/18630877
  • {PUB} PubChem --- Functionalised cyclopentadienyl zirconium compounds as potential anticancer drugs --- https://pubmed.ncbi.nlm.nih.gov/18827935
  • {PUB} PubChem --- Hydroamination/Cyclization of Aminoalkenes Using Cationic Zirconocene and Titanocene Catalysts --- https://pubmed.ncbi.nlm.nih.gov/15484241
  • {PUB} PubChem --- Intramolecular hydroamination/cyclisation of aminoallenes mediated by a cationic zirconocene catalyst: a computational mechanistic study --- https://pubmed.ncbi.nlm.nih.gov/16932821
  • {PUB} PubChem --- Reactive Intermediates Formed During Olefin Polymerization by Methylalumoxane-Activated ansa-Zirconocene Catalysts: Identification of a Chain-Carrying Intermediate by NMR Methods --- https://pubmed.ncbi.nlm.ni
  • 1291-32-3 H76122 Bis(cyclopentadienyl)zirconium dichloride
二氯二茂锆

    化学属性

    Mol. FormulaC10H10Cl2Zr
    Mol. Weight292.32
    Density1.422
    Melting Point242-245°C
    TSCAYes
    Boiling Point124-125 °C at 15 mmHg
    Solubility水解
    Stability对湿度敏感
    Flash Point124-125°C/15mm
    Appearance white to off-white pwdr.
    RedoxReduction

    *以上化合物性质及应用等信息仅供参考