Vinylmagnesium bromide 乙烯基溴化镁

规格: 1.0 M solution in THF, SpcSeal
CAS: 1826-67-1
产品编号: H76970
MDL: MFCD00000042
品牌: INFI
Chemical NameVinylmagnesium bromide solution
CAS Number1826-67-1
EC Number217-375-3
Beilstein Registry Number3535841
MDL NumberMFCD00000042
Reaxys-RN3535841
PubChem Substance ID87577845
Synonym Norman reagent Ethenylmagnesium bromide Vinyl magnesium bromide VINYLMAGNESIUM BROMIDE Vinyl-magnesium bromide 0.98g/ml，20℃ VINYLMAGNESIUM BROMIDE SOLUTION, ~1.0 M IN THF 乙烯基溴化镁四氢呋喃溶液 VINYLMAGNESIUMBROMICLC Vinylmagnesium bromide Bromovinylmagnesium Vinylmagnesium bromide0.7M solution in THFAcroSeal§3 Vinylmagnesium bromide(1.0mol/Lsolytion in tetrahydro-furan) Bromvinylmagnesium bromoethenyl-magnesiu Magnesium, bromovinyl- Vinylmagnesium Bromide 0.7 M in Tetrahydrofuran Vinylmagnesium bromide, 0.8-1.0 M in THF 乙烯基溴化镁 Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L) VINYLMAGNESIUM BROMIDE, 1.0M SOLUTION IN TETRAHYDROFURAN 溴化乙烯基镁 乙烯基溴化镁;溴化乙烯镁 Vinylmagnesium bromide, 0.8-1.0 M in THF, packaged under Argon in resealable ChemSeal bottles vinylmagnesiumbromidesolution bromovinylmagnesium 溴化乙烯鎂 Vinylmagnesium bromide, 0.7M solution in THF 溴化乙烯镁四氢呋喃溶液 溴化乙烯镁(1MOL/L四氢呋喃溶液) 乙烯基溴化镁 溶液 Magnesium, bromoethenyl-
Chemical Name Translation乙烯基溴化镁
InChIKeyXHHHAXOHMKAOSL-UHFFFAOYSA-M
LabNetwork Molecule IDLN00223958
IUPAC Namemagnesium;ethene;bromide
  • ⑴. 由于镁原子直接和碳链相连，极化作用使邻近镁原子的那个碳原子呈负电性，使得C-Mg键极具反应活性。为了保证该产品不发生其他反应，反应一般在醚类溶剂里进行,常用的有乙醚或四氢呋喃。
  • ⑵. 有强烈的亲核性质，可与物质中的活泼氢（如水、乙醇的羟基氢、乙炔的末端氢）反应,生成相应的烃基。
  • ⑶. 与CO2或O2的反应，可以与二氧化碳或氧气发生亲核加成反应生成增加一个碳的羧酸或同碳数的过氧化合物.格氏试剂与二氧化碳的加成反应在有机合成中也有着重要的意义,不仅通过生成新的 C-C 键实现了碳链的增长,而且恰到好处地
  • {SA} Aldrich MSDS 1 , 1837:D / Corp MSDS 1 (2), 3605:B / Structure Index 1 , 483:B:6
  • {PUB} PubChem|Springer Nature --- A concise synthesis of a promising protein kinase C inhibitor: D-erythro-sphingosine --- https://pubmed.ncbi.nlm.nih.gov/17328238
  • {PUB} PubChem|Springer Nature --- Capillary isoelectric focusing with pH 9.7 cathode for the analysis of gastric biopsies --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4429874
  • {PUB} PubChem|Springer Nature --- Development of new dihydropyran linker for solid-phase reaction --- https://pubmed.ncbi.nlm.nih.gov/10615865
  • {PUB} PubChem|Springer Nature --- Efficient, large-scale synthesis and preclinical studies of MRS5698, a highly selective A3 adenosine receptor agonist that protects against chronic neuropathic pain --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4529848
  • {PUB} PubChem|Springer Nature --- Isotope-Coded Two-Dimensional Maps: Tagging with Deuterated Acrylamide and 2-Vinylpyridine --- https://pubmed.ncbi.nlm.nih.gov/18369855
  • {PUB} PubChem|Springer Nature --- Ring-Fluorinated Analog of Methyl Eugenol: Attractiveness to and Metabolism in the Oriental Fruit Fly, Bactrocera Dorsalis (Hendel) --- https://pubmed.ncbi.nlm.nih.gov/19198948
  • {PUB} PubChem|Springer Nature --- Synthesis and antiviral evaluation of novel 3′- and 4′-doubly branched carbocyclic nucleosides as potential antiviral agents --- https://pubmed.ncbi.nlm.nih.gov/14723348
  • {uni_hamburg} Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • {uni_hamburg} Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New
    • 1826-67-1 H76970 Vinylmagnesium bromide 乙烯基溴化镁

    化学属性

    Mol. FormulaC2H3BrMg
    Mol. Weight131.26
    Density0.98
    Flash Point1 °F
    Solubility剧烈反应
    Stability对热和湿度敏感
    Danger-Level-
    pH-:-
    Redox-

    *以上化合物性质及应用等信息仅供参考