{PUB} Crystallography Open Database (COD)|PubChem --- Multiple Silicon-Hydrogen Bond Activations at Adjacent Rhodium and Iridium Centers --- https://pubmed.ncbi.nlm.nih.gov/21077657

{PUB} Crystallography Open Database (COD)|PubChem|The Cambridge Structural Database --- Reaction of alkyne with dinickel-diphenylsilyl complexes. Preparation of an emissive disilane via consecutive Si-C and Si-Si bond-making reactions --- https://pubmed.ncbi.nlm.nih.gov/22241522

{ALF} CsF promotes the reduction of aldehydes and ketones to alcohols: J. Organomet. Chem., 148, C1 (1978); 172, 143 (1979). Esters can be reduced at elevated temperatures: Synthesis, 558 (1981). Aldehydes and ketones are also reduced in the presence of TBAF: J. Org. Chem., 53, 5415 (1988).

{ALF} In combination with an equivalent of Titanium(IV)­ isopropoxide, A13703, a mild, one-pot reduction of tertiary amides to aldehydes can be accomplished in high yield. The initial product is the enamine which can be readily hydrolyzed in situ to the aldehyde: Angew. Chem. Int. Ed., 35, 1515 (1996):

{ALF} In the presence of Tetrakis(triphenyl­phosphine)­palladium(0)­, 10548, effects the reductive cleavage of allylic acetates: J. Org. Chem., 48, 3545 (1983). With the same catalyst and a Lewis acid such as zinc chloride, ɑß-unsaturated aldehydes, ketones and esters are reduced to their saturated counterparts: J. Am. Chem. Soc., 108, 7314 (1986).

{PUB} P

{ALF} Protection of diols as diphenylsilylenes can be effected in the presence of CsF: J. Organomet. Chem., 282, 155 (1985). See Diphenyl­dichlorosilane, A12051, and Appendix 4.

{PUB} PubChe

{PUB} PubChem --- Designing the “Search Pathway” in the Development of a New Class of Highly Efficient Stereoselective Hydrosilylation Catalysts --- https://pubmed.ncbi.nlm.nih.gov/15744702

{PUB} PubChem --- Further Studies toward the Stereocontrolled Synthesis of Silicon-Containing Peptide Mimics --- https://pubmed.ncbi.nlm.nih.gov/20423092