Tricaprylylmethylammonium chloride 甲基三辛基氯化铵

规格: 98%
CAS: 5137-55-3
产品编号: H90737
MDL: MFCD00011862
品牌: INFI
Chemical NameMethyltrioctylammonium chloride
MDL NumberMFCD00011862
CAS Number5137-55-3
EC Number264-120-7
Beilstein Registry Number4039255
Synonym ADOGEN 464 ALIQUAT 336 ALIQUAT(TM) 336 Aliquat® 128 Aliquat® 336 替代产品 氯化甲基三辛基铵 甲基三辛基氯化铵 Methyltri-n-octylammonium chloride Methyltri-n-octylammonium chlorideTricaprylylmethylammonium chloride Methyltricaprylylammonium chloride Methyltrioctylammonium chloride; Trioctylmethylammonium chloride; Tricaprylmethylammonium chloride; Aliquat 336; Capriquat TOMAC TRIOCTYLMETHYLAMMONIUM CHLORIDE Tricaprylmethylammonium chloride Trioctylmethylammonium chloride, Methyltri-n-octylammonium chloride aliquat methyltricaprylylammoniumchloride methyltrioctyl-ammoniuchloride n-methyl-n,n-dioctyl-1-octanaminiuchloride n-methyl-n,n-dioctyl-1-octanaminiumchloride 甲基三辛基氯化铵 甲基三辛基氯化铵(R=C8-C10) 甲基三辛基氯化铵/氯化甲基三辛基
PubChem Substance ID57652193
Reaxys-RN4039255
Chemical Name Translation甲基三辛基氯化铵
Wiswesser Line Notation8K8&8&1 &G
LabNetwork Molecule IDLN00197497
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6600 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 280 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsena

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3300 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LD50 - Lethal d

Signal word Danger
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
    Risk Statements
    • R22 Harmful if swallowed 吞咽有害
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R38 Irritating to skin 刺激皮肤
    • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
    • R50/53
      Precautionary statements
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P310
      • P301+P310+P330
      • P305+P351+P338
      • P332+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
      • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H301 Toxic if swallowed 吞食有毒
        • H315 Causes skin irritation 会刺激皮肤
        • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
        • H318 Causes serious eye damage 严重伤害眼睛
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves
          RTECSUZ2997500
          Packing GroupIII
          UN Number 2810 UN2810
          Storage condition 储存温度2-8℃,充氩保存 密封保存 易吸潮,密封保存 0-10°C Hygroscopic 0-10
          Hazard Codes 6.1 Xn,N Xn;N
          Hazard Class6.1
        • 相转移试剂
        • {ALF} Mixture of C8-C10; predominantly C8.
        • {ALF} Widely used lipophilic phase-transfer catalyst. Catalyzes the synthesis of long-chain alkyl azides from the bromides in water or formamide: Tetrahedron Lett., 30, 1245 (1989), the formation and saponification of hindered esters with KOH in the absence of solvent: J. Org. Chem., 51, 740 (1986), the solvent-free SNAr reactions of halopyridines: Heterocycles, 32, 1947 (1991), and dehydrohalogenation of vic-dibromides to alkynes: Org. Prep. Proced. Int., 21, 232 (1989). Catalyzes the solvent-free liquid-liquid phase-transfer hydroboration of olefins, using aqueous NaBH4: Synlett, 997 (2000). See Appendix 2.
        • {ALF} Aliquat is a registered trademark of Cognis Corporation.
        • 5137-55-3 H90737 Tricaprylylmethylammonium chloride
甲基三辛基氯化铵

          化学属性

          Mol. FormulaC25H54ClN
          Mol. Weight404
          Density0.884
          Refractive index1.4465
          Flash Point132°C(lit.)
          TSCAYes
          Boiling Point>240°
          Melting Point-20°C
          Appearance 淡黄色粘稠液体或膏体,沸点 225℃,熔点 -20℃
          Stability易吸潮