| Chemical Name | Triethylborane |
| MDL Number | MFCD00009022 |
| CAS Number | 97-94-9 |
| Synonym |
Triethylborane (1.0 M in THF)
Triethylborane (ca. 11% in Tetrahydrofuran, ca. 1mol/L) |
| PubChem Substance ID | 87577677 |
| Beilstein Registry Number | 1731462 |
| EC Number | 202-620-9 |
| Reaxys-RN | 1731462 |
| Merck Number | 9668 |
| Chemical Name Translation | 三乙基硼 |
| Wiswesser Line Notation | 2B2&2 |
| LabNetwork Molecule ID | LN00164556 |
| InChI | InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3 |
| Canonical SMILES | CCB(CC)CC |
| IUPAC Name | triethylborane |
Usually used as catalyst for Allylation of aldehydes,Decarboxylative C-C bond cleavage reactions,Regioselective hydroxyalkylation of unsaturated oxime ethers.And also used as reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes,synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.
{PUB} Crystallography Open Database (COD)|PubChem|The Cambridge Structural Database --- Deoxygenative [1,2]-Hydride Shift Rearrangements in Nucleoside and Sugar Chemistry: Analogy with the [1,2]-Electron Shift in the Deoxygenation of Ribonucleotides by Ribonucleotide Reductases1 --- https://pubmed.ncbi.nlm.nih.gov/17918996
{ALD} Merck: 14,9668
{ALD} Merck: 14,9668 Beilstein:4(4)4359
{PUB} Nature Chemistry|PubChem|Springer Nature --- Towards high-performance sustainable polymers via isomerization-driven irreversible ring-opening polymerization of five-membered thionolactones --- https://pubmed.ncbi.nlm.nih.gov/34824460
{PUB} PubChem --- A convenient allylsilane-N-acyliminium route toward indolizidine and quinolizidine alkaloids --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2148044
{PUB} PubChem --- Catalytic Intermolecular Enal−Alkyne [3 + 2] Reductive Cycloadditions --- https://pubmed.ncbi.nlm.nih.gov/17061877
{PUB} PubChem --- Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor --- https://pubmed.ncbi.nlm.nih.gov/18611014
{PUB} PubChem --- Direct observation of the unstable intermediates in radical addition reaction by using an interfacing microchip combined with an NMR --- https://pubmed.ncbi.nlm.nih.gov/17924352
{PUB} PubChem --- Erratum: Structure elucidation of the intermediate in triethylborane‐mediated radical addition of oxime ethers with 2D‐ and 3D‐DOSY NMR --- https://pubmed.ncbi.nlm.nih.gov/16729260
{PUB} PubChem --- Et3B-Induced Radical Addition of N,N-Dichlorosulfonamide to Alkenes and Pyrrolidine Formation via Radical Annulation --- https://pubmed.ncbi.nlm.nih.gov/12688798
{PUB} PubChem --- Hydroxyalkylation of α-C−H Bonds of Tetrahydrofuran with Aldehydes in the Presence of Triethylborane and tert-Butyl Hydroperoxide --- https://pubmed.ncbi.nlm.nih.gov/12530897
{PUB} PubChem --- Macrocyclization by Nickel‐Catalyzed, Ester‐Promoted, Epoxide–Alkyne Reductive Coupling: Total Synthesis of (−)‐Gloeospor