| Chemical Name | Samarium(II) Iodide |
| MDL Number | MFCD00058873 |
| PubChem Substance ID | 24861467 |
| CAS Number | 32248-43-4 |
| Merck Number | 8349 |
| EC Number | 203-726-8 |
| Synonym |
Samarium diiodide
Samarium(II) Iodide (ca. 0.1mol/L in Tetrahydrofuran) |
| Chemical Name Translation | 二碘化钐(II) |
| LabNetwork Molecule ID | LN01295309 |
| Canonical SMILES | I[Sm]I |
⑴.常温常压下为蓝色至深蓝色液体,具有特殊气味。在极性有机溶剂中有一定的溶解度,通常在THF,HMPA中使用。刺激皮肤和粘膜。
⑵. 遇水分解生成碱式碘化钐和氢气。有强还原性。具有较强的吸湿性,对氧气特别敏感,需要在惰性气体保护下制备和使用。一般保存于约0.1mol/L的四氢呋喃溶液中。
⑶. 碘化钐(SmI2)是有机合成中一个具有广泛用途的试剂。它参与的主要反应包括:自由基环化反应;羰基-烯烃偶联反应;频哪偶联反应;羟醛缩合反应;Barbier反应;Reformatsky反应等。
①. SmI2最基本
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1. Synthesis , 1309, (2007)
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Merck 14 ,8349
{uni_hamburg} Short: II/25A
Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules
Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
Editor: Kuchitsu, K.
Source: Landolt-Börnstein, New Series
Volume: II/25A
Year: 1998
Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules
ISBN: 3-540-61713-2
ISBN: 978-3-540-61713-6
Internet Resource: DOI:10.1007/b59072
RefComment: VII, 359 pages. Hardcover
Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
{uni_hamburg} Short: III/7a
Title: Crystal Structure Data of Inorganic Compounds: Key Elements: F, Cl , Br, I ( VII th Main Group) . Halides and Complex Halides
Author: Pies, W.; Weiss, A.
Editor: Hellwege, K.-H.; Hellwege, A.M.
Source: Landolt-Börnstein, New Series
Volume: III/7a
Page: 1-647
Year: 1973
ISBN: 3-540-06166-5
ISBN: 978-3-540-06166-3
Internet Resource: DOI:10.1007/b19972
RefComment: 1 fig., XXXII, Hardcover
Abstract: Volume III/7 contains structure data on those compounds which contain at least one of the elements F, Cl, Br, I, O, N, and P and cannot be called "organic". The structure data of the remaining inorganic compounds and the elements are dealt with in volumes III/6 and III/14, while the organic compounds are treated in volumes III/5 and III/10. The systematic arrange-ment is bas