Boron tribromide 三溴化硼正己烷溶液

规格: 1.0 M solution in hexanes, SpcSeal
CAS: 10294-33-4
产品编号: H41021
MDL: MFCD00011312
品牌: INFI
Chemical NameBoron tribromide
Synonym BORON TRIBROMIDE, REAGENTPLUS, >=99% BORON TRIBROMIDE, 99.995% 晶碱石 boron (III) bromide BORON TRIBROMIDE, REAGENTPLUS, 99.9% Bortribromid 三溴化硼(0402禁空运) boronbromide(bbr3) 三溴化硼,1M在二氯甲烷溶剂中 Boron tribromide tribromoborane 三溴化硼 BORON TRIBROMIDE, 1.0M SOLUTION IN HEPTA NE tribromo-boran Boron bromide (BBr3) BORON TRIBROMIDE SOLUTION, ~1 M IN DICHL OROMETHANE Borane,tribromo- Boron,tribromo- trona 天然碱 BORON TRIBROMIDE BBr3 三溴化硼 溶液 Borane, tribromo- BORON TRIBROMIDE, 1.0M SOLUTION IN HEXAN ES Tribromoboron tribromuredebore 溴化硼 boron tribromide 三溴硼烷(爆炸,禁止销售)BORON TRIBROMIDE, 99.9% 三溴硼烷 丝光晶碱石 BORON TRIBROMIDE, 1.0M SOLUTION IN DICHL OROMETHANE Boron tribromide Solution BORON BROMIDE Boron bromide 溴化硼;天然碱 三溴化硼, 99% MIN 碳酸钠石 tribromoboron Tribromoborane 天然碱;碳酸钠石 BBr3
CAS Number10294-33-4
PubChem Substance ID125307031
EC Number233-657-9
MDL NumberMFCD00011312
Reaxys-RN3903058
Merck Number1347
Beilstein Registry Number2384789
Chemical Name Translation三溴化硼
LabNetwork Molecule IDLN00163667
  • ⑴.易被水和醇等分解，受热会爆炸，对人体组织有强烈刺激作用，其蒸气剧毒，腐蚀性较强，具有强吸水性，见光、遇热易分解，接触空气冒白烟。为强路易式酸，能与碱反应形成络合物和加成物。
  • ⑵.在干燥空气中不变化。溶于无机酸并剧烈起泡。天然碱产于不同的盐湖沉积物中，主要产于碱湖及古代沉积矿床中，常与针碳钠钙石、水碱、泡碱、石盐、芒硝、钙芒硝、无水芒硝和石膏共生。遇空气中的湿气很容易水解。
  • ⑶.重要的工业原料，广泛用于玻璃、化工、轻工、纺织、漂染、冶金、石油加工、医药、食品等方面。
  • ⑷.用作半导体的掺杂材料，有机
  • 用作有机合成的催化剂、中间体和溴化剂，制造高纯硼及其它有机硼化合物的原料。
  • {ALF} Reagent for cleavage of ethers: Synthesis, 249 (1983). Converts alcohols to alkyl bromides under mild conditions: Tetrahedron Lett., 35, 1051 (1994). Cleavage of N-methoxymethyl: Tetrahedron Lett., 42, 8633 (2001), or N-benzyl: Tetrahedron Lett., 45, 4093 (2004) protecting groups can also be achieved under mild conditions. Alkynes undergo bromoboration; the products can be transformed, e.g. to trisubstituted alkenes: Tetrahedron Lett., 29, 1811 (1988), or enyne-allenes: Tetrahedron Lett., 35, 1829 (1994).
  • {uni_hamburg} Short: II/25A
  • {ALD} Merck:14,1347
  • {ALF} Reagent for cleavage of ethers. For a brief feature of uses of the reagent in organic synthesis, see: Synlett, 1636 (2005). See also preceding entry.
  • {ALF} Reagent for cleavage of ethers: Synthesis, 249 (1983). Converts alcohols to alkyl bromides under mild conditions: Tetrahedron Lett., 35, 1051 (1994). Cl
    • 10294-33-4 H41021 Boron tribromide 三溴化硼正己烷溶液

    化学属性

    Mol. FormulaBBr3
    Mol. Weight250.54
    Boiling Point91.3°C
    Density0.88
    Melting Point-46°C
    Refractive index1.4340
    TSCAYes
    Flash Point-4°C(lit.)
    Vapor Density8.6 (vs air)
    Vapor Pressure40 mmHg ( 14 °C)
    Solubility溶于四氯化碳。
    Stability对热、光线、湿度敏感
    Appearance pale yellow to orange liq.
    pH-:A
    Danger-Level-
    Redox-

    *以上化合物性质及应用等信息仅供参考