Bis(acetylacetonato)dioxomolybdenum(VI) 乙酰丙酮钼

规格: 99%
CAS: 17524-05-9
产品编号: H12589
MDL: MFCD00011506
品牌: INFI
Chemical Name乙酰丙酮钼
MDL NumberMFCD00011506
Synonym Bis(acetylacetonato)dioxomolybdenum(VI) Molybdenyl acetylacetonate MoO2(acac)2 Molybdenum dioxydiacetylacetonate 乙酰丙酮钼 Molybdenum diacetylacetonate dioxide Molybdenum dioxide bis(acetylacetonate)
EC Number241-522-0
CAS Number17524-05-9
PubChem Substance ID87572516
Reaxys-RN4141174
Beilstein Registry Number2384789
Chemical Name Translation乙酰丙酮钼
InChIKeySKMUJBBRXZPAJY-UZUXQKAQSA-L
LabNetwork Molecule IDLN01373463
GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
    • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
    • R22 Harmful if swallowed 吞咽有害
      WGK Germany3
      Precautionary statements
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P304+P340+P312
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P332+P313
      • P302+P352+P312+P362+P364
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P301+P312+P330
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
        Signal word
        Hazard statements
        • H332 Harmful if inhaled 吸入有害
        • H315 Causes skin irritation 会刺激皮肤
        • H302 Harmful if swallowed 吞食有害
        • H312 Harmful in contact with skin 皮肤接触有害
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H351 Suspected of causing cancer 怀疑致癌
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H302+H312+H332
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Hazard Codes Xn Xi
        • 构成一种功能性的复合物用于研究钼血清转移酶（oxotransferase molybdenum）
        • {ALF} Mild catalyst for the deprotection of acetals in high yield: Synth. Commun., 25, 2529 (1995).
        • {ALF} In the presence of a phase-transfer catalyst, catalyzes the high yield oxidation of secondary alcohols to ketones with sodium percarbonate in acetonitrile or 1,2-dichloroethane. Primary alcohols give moderate to good yields of aldehydes: Synlett, 439 (1996).
          • 17524-05-9 H12589 Bis(acetylacetonato)dioxomolybdenum(VI) 乙酰丙酮钼

          化学属性

          Mol. FormulaC10H14MoO6
          Mol. Weight326.18
          TSCANo
          Melting Point184
          Solubility8.52 G/100 ML (20 ºC)
          Density1.64

          *以上化合物性质及应用等信息仅供参考