Silver(I) fluoride 氟化银(I)

规格: 98%
CAS: 7775-41-9
产品编号: H13509
MDL: MFCD00003410
品牌: INFI
Chemical NameSilver fluoride
CAS Number7775-41-9
Alfabeta NameSILVERFLUORIDE I()
MDL NumberMFCD00003410
EC Number231-895-8
PubChem Substance ID165912
Synonym Silver(I) fluoride {LY} Silver(I) fluoride {} {LY} Silver(I) fluoride {} {} {LY} Silver(I) fluoride {} {} {} {LY} Silver(I) fluoride {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {
Merck Number14,8514
Beilstein Registry Number2384789
Chemical Name Translation氟化银
LabNetwork Molecule IDLN00117348
InChIInChI=1S/Ag.FH/h;1H/q+1;/p-1
Canonical SMILES[Ag]F
GHS Symbol
Warnings HYGROSCOPIC, CORROSIVE
WGK Germany3
Hazard Codes 8 C
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H301+H311+H331
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
    Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
    RTECSVW4250000
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P310
    • P303+P361+P353
    • P304+P340+P310
    • P305+P351+P338
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
      Signal word Danger
      Safety Statements
      • S25 Avoid contact with eyes 避免眼睛接触；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        UN Number 3260
        Risk Statements
        • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
        • R34 Causes burns 会导致灼伤
        • R35 Causes severe burns 会导致严重灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light & Moisture Sensitive & Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {
          Packing GroupII
        • 用于由大位阻的三烷基甲硅烷基乙炔制备溴乙炔.也用于乙酰苯胺与三烷氧基硅烷的钯催化交叉偶联反应.
        • {SA} 1. Tetrahedron 62 , 4081, (2006)
        • {SA} 2. J. Am. Chem. Soc. 129 , 6066, (2007) 摘要
        • {SA} Corp MSDS 1 (2), 3095:B / RegBook 1 (3), 3311:D / Sax 6 , 2403
        • {SA} Fieser 2 ,364 / Fieser 5 ,581 / Fieser 6 ,514
        • {SA} Merck 14 ,8514
        • {uni_hamburg} Short: II/24A
        • Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules
        • Author: Demaison, J.; Hübner, H.; Wlodarczak, G.
        • Editor: Hüttner, W.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/24A
        • Year: 1998
        • Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules
        • ISBN: 3-540-63267-0
        • ISBN: 978-3-540-63267-2
        • Internet Resource: DOI:10.1007/b60165
        • RefComment: VIII, 286 pages. Hardcover
        • Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
        • {uni_hamburg} Short: III/23C1
        • Title: Electronic Structure of Solids: Photoemission Spectra and Related Data: Noble Metals, Noble Me
          • 7775-41-9 H13509 Silver(I) fluoride 氟化银(I)

          化学属性

          Mol. FormulaAgF
          Mol. Weight126.87
          Boiling Point1150 °C at 760 mmHg
          TSCAT
          Melting Point≥300°C
          Density5.85
          SolubilitySoluble in HF, ammonia, CH3CN
          Flash Point1150°C
          Appearance 它是黄棕色固体，熔点435℃，暴露于潮湿空气时变黑。与其他卤化银不同，氟化银可溶于水，溶解度为1.8 kg/L[1]，也可溶于乙腈。Ag-F键长:246pm,小于其它卤化银．共价半径为246pm，与Ag-F键长相同，应区别于其它卤化银．键型为离子键，也与其它卤化银相异．晶格类型类似于氯化钠，与氯化银／溴化银相同（碘化银晶格类型类似于硫化锌．）（其它卤化银均有共价键倾向：氯化银／溴化银的键型为过渡键，碘化银键型为共价键）

          *以上化合物性质及应用等信息仅供参考