4-Picoline 4-甲基吡啶

规格: 99%
CAS: 108-89-4
产品编号: H23747
MDL: MFCD00006440
品牌: INFI
Chemical Name4-Methylpyridine
MDL Number-
CAS Number108-89-4
Synonym 4-Methylpyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number203-626-4
Merck Number7402
Beilstein Registry Number104586
PubChem Substance ID7963
Chemical Name Translation4-甲基吡啶
Reaxys-RN104586
Wiswesser Line NotationT6NJ D1
LabNetwork Molecule IDLN00194204
InChIInChI=1S/C6H7N/c1-6-2-4-7-5-3-6/h2-5H,1H3
Canonical SMILESCC1=CC=NC=C1
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 57(9-10),64,1992

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 57(9-10),64,1992

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent k

TYPE OF TEST

RTECSUT5425000
Packing GroupIII
UN Number UN2313 UN 1992 3/PG 3
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R10 Flammable 易燃
    Safety Statements
    • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    • S36 Wear suitable protective clothing 穿戴适当的防护服；
    • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      Storage condition 4 RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
      WGK Germany1
      Hazard statements
      • H315 Causes skin irritation 会刺激皮肤
      • H311 Toxic in contact with skin 皮肤接触中毒
      • H335 May cause respiratory irritation 可能导致呼吸道刺激
      • H319 Causes serious eye irritation 严重刺激眼睛
      • H302+H332
      • H226 Flammable liquid and vapour 易燃液体和蒸气
      • H332 Harmful if inhaled 吸入有害
      • H302 Harmful if swallowed 吞食有害
        Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
        Precautionary statements
        • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
        • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
        • P305+P351+P338
        • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
        • P332+P313
        • P241+
        • P501 Dispose of contents/container to..… 处理内容物/容器.....
        • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
        • P301+P312+P330
        • P337+P313
        • P403+P233
        • P303+P361+P353
        • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
        • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
        • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
        • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
        • P304+P340+P312
        • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
        • P305+P351+P338+P337+P313
        • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
          Signal word
          Hazard Codes T
          Hazard Class3
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 用于医药工业
        • {ALD} Merck:14,7402
        • Beilstein:20,240
        • {ALD} Merck:14,7402
          • 108-89-4 H23747 4-Picoline 4-甲基吡啶

          化学属性

          Mol. FormulaC₆H₇N
          Mol. Weight93.13
          Density0.95
          Refractive index1.5020 to 1.5060
          Flash Point56.67°C
          TSCAYes
          Boiling Point
          Melting PointNo Data Available
          Autoignition Point1000 °F
          Vapor Density3.2 (vs air)
          Vapor Pressure4 mmHg ( 20 °C)
          Solubility溶于水、乙醇和乙醚。
          Appearance 4-甲基吡啶(108-89-4)为无色液体。熔点3.8℃，沸点143.1℃（145℃），相对密度0.9571（15/4℃），折光率1.5064（17℃），闪点56℃。溶于水、醚和醇。
          pH:A

          *以上化合物性质及应用等信息仅供参考