1,2-Bis(bromomethyl)benzene 1,2-双(溴甲基)苯

规格: 97%
CAS: 91-13-4
产品编号: H50166
MDL: MFCD00000175
品牌: INFI
Chemical Name1,2-Bis(bromomethyl)benzene
Synonym 1,2-Bis(bromomethyl)benzene {LY} 1,2-Bis(bromomethyl)benzene {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis(bromomethyl)benzene
CAS Number91-13-4
PubChem Substance ID87566927
EC Number202-042-7
Beilstein Registry Number637159
MDL NumberMFCD00000175
Reaxys-RN637159
Chemical Name Translation1,2-二(溴甲基)苯
LabNetwork Molecule IDLN00009339
InChIInChI=1S/C8H8Br2/c9-5-7-3-1-2-4-8(7)6-10/h1-4H,5-6H2
Canonical SMILESBrCC1=CC=CC=C1CBr
GHS Symbol
WGK Germany2
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
    Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
    Hazard Codes 6.1 C
    Precautionary statements
    • P234 Keep only in original container. 只保留在原来的容器中。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
    • P301+P330+P331+P310
    • P303+P361+P353+P310+P363
    • P304+P340+P310
    • P305+P351+P338
    • P305+P351+P338+P310
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
    • P403+P233
    • P405 Store locked up. 上锁保管。
    • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R34 Causes burns 会导致灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          UN Number 2928 UN 3448 6.1/PG 2
          Packing GroupII
          Hazard Class6.1/8
          Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
        • {ALF} Dialkylating agent for the formation of a variety of benzo-fused carbocyclic and heterocyclic ring systems, e.g. five-membered with Meldrum's acid (Isopropyl­idene malonate, A15603): Org. Prep. Proced. Int., 24, 185 (1992), 7-membered with Dimethyl­ acetone-1,3-dicarboxyl­ate, A14969: J. Org. Chem., 54, 5237 (1989), as well as macrocycles and cryptands; see, e.g.: J. Org. Chem., 57, 6112 (1992). Reaction with 1,2- and 1,3-diols has been used a method of protection; the diol can be regenerated by hydrogenolysis: Synth. Commun., 19, 3363 (1989).
        • {ALF} Reductive debromination with activated Ni provides a simple route to o-xylylene, which can be trapped by dienophiles: J. Org. Chem., 53, 339 (1988):
        • {uni_hamburg} Short: III/31b
        • {ALF} o-Xylylene can also be generated using Zn metal and ultrasound: J. Org. Chem., 47, 751 (1982), or NaI in DMF: Chem. Pharm. Bull., 22, 2159 (1974).
          • 91-13-4 H50166 1,2-Bis(bromomethyl)benzene 1,2-双(溴甲基)苯

          化学属性

          Mol. FormulaC8H8Br2
          Mol. Weight263.96
          Density1.96
          Melting Point91-94°C
          TSCAYes
          Solubility可溶, HYDROLYSES
          Boiling Point140 °C at 20 mmHg

          *以上化合物性质及应用等信息仅供参考