1-Bromo-2-fluorobenzene 邻氟溴苯

规格: 98%
CAS: 1072-85-1
产品编号: H54429
MDL: MFCD00000282
品牌: INFI
Chemical Name1-Bromo-2-fluorobenzene
CAS Number1072-85-1
Alfabeta NameBROMOFLUOROBENZENE 12---
MDL NumberMFCD00000282
Synonym 1-Bromo-2-fluorobenzene {LY} 1-Bromo-2-fluorobenzene {} {LY} 1-Bromo-2-fluorobenzene {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number214-018-3
Beilstein Registry Number1071819
PubChem Substance ID61259
Reaxys-RN1071819
Chemical Name Translation邻氟溴苯
InChIKeyIPWBFGUBXWMIPR-UHFFFAOYSA-N
Wiswesser Line NotationFR BE
LabNetwork Molecule IDLN00115991
InChIInChI=1S/C6H4BrF/c7-5-3-1-2-4-6(5)8/h1-4H
Canonical SMILESFC1=CC=CC=C1Br
GHS Symbol
Warnings IRRITANT, FLAMMABLE
Signal word Warning
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
    Risk Statements
    • R10 Flammable 易燃
    • R22 Harmful if swallowed 吞咽有害
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P312+P330
      • P303+P361+P353
      • P305+P351+P338
      • P332+P313
      • P337+P313
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          RTECSDA1050000
          Packing GroupIII
          UN Number 1993
          Hazard Codes 3 Xn
          Hazard Class3
          Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
        • 医药、农药、液晶材料中间体。
        • {ALF} On treatment with Mg: J. Org. Chem., 49, 4518 (1984), or n-BuLi: Tetrahedron, 48, 4379 (1992), benzyne is generated, which undergoes [4+2] cycloadditions with furans or pyrroles.
        • {uni_hamburg} Short: III/35D2
        • {uni_hamburg} Short: III/38B
        • {ALF} Whereas n-BuLi effects bromine-metal exchange, lithiation with LDA at -75o results in deprotonation ortho to F; subsequent reaction with electrophiles provides access to mixed dihalo derivatives such as 3-bromo-2-fluorobenzoic acid: Tetrahedron Lett., 36, 881 (1995). Improved yields are obtained by the use of lithium 2,2,6,6-tetramethylpiperidide (LTMP) as base: Tetrahedron Lett., 37, 6551 (1996).
        • {ALD} Beilstein: 5,IV,678
          • 1072-85-1 H54429 1-Bromo-2-fluorobenzene 邻氟溴苯

          化学属性

          Mol. FormulaC6H4BrF
          Mol. Weight175.00
          Boiling Point78-82 °C at 50 mmHg
          TSCAT
          Density1.601
          Refractive index1.5330 to 1.5350
          Flash Point50.2°C
          Melting Point-8 °C
          Solubility不溶
          Appearance 淡黄色液体。沸点155℃-157℃，闪点43℃，折光率1.5340，比重1.601。

          *以上化合物性质及应用等信息仅供参考