Bis(cyclopentadienyl)zirconium chloride hydride 氢氯二茂锆

规格:
CAS: 37342-97-5
产品编号: HXYJ0000003360
MDL: MFCD02089401
品牌: Bellen
Chemical NameBis(Cyclopentadienyl)Zirconium Chloride Hydride
Synonym Bis(cyclopentadienyl)chlorohydrozirconium {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} { {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohydrozirconium {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)chlorohy
PubChem Substance ID87577928
EC Number253-479-5
Merck Number8396
Chemical Name Translation氢氯二茂锆
InChIKeyUVWUHPCWBZSERX-UHFFFAOYSA-M
MDL NumberMFCD02089401
CAS Number37342-97-5
Canonical SMILES[][Zr]([H])(Cl)[].c1cccc1.c2cccc2
GHS Symbol
WGK Germany3
Precautionary statements
  • P422 Store contents under… 存储目录在…之下。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P310
  • P301+P330+P331
  • P402+P404
  • P303+P361+P353+P310+P363
    Hazard statements
    • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
    • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
      Signal word
      Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S33 Take precautionary measures against static discharges 对静电采取预防措施；
      • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        Packing GroupII
        UN Number 3131
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
        • R34 Causes burns 会导致灼伤
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light, Air & Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
          Hazard Codes F,C
          Hazard Class4.3/8
          Restrict -
        • 转化氨基化合物生成醛类化合物；石蜡和炔烃的功能化试剂。
        • {ALF} Reagent for selective reduction of secondary carboxamides to imines, a transformation otherwise difficult to achieve since imines are normally more easily reduced than amides: J. Org. Chem., 61, 4115 (1996); tertiary amides can also be reduced to aldehydes at room temperature: J. Am. Chem. Soc., 122, 11995 (2000). Reduction of phosphine oxides and phosphine sulfides to phosphines under mild conditions has also been reported: Tetrahedron Lett., 38, 5997 (1997).
        • {ALF} Catalyzes the hydroboration of alkynes with Pinacolborane, L17558, to form alkenylboronates with high regio- and stereoselectivity: Organometallics, 14, 3127 (1995). Alkenes are similarly converted to alkylboronates: J. Am. Chem. Soc., 118, 909 (1996).
        • {ALF} Reaction with alkenes (hydrozirconation) results in zirconocene alkyl chlorides: Tetrahedron Lett., 28, 3895 (1987). Useful products are obtained by reaction of these with various electrophiles. With O-(mesitylsulfonyl)hydroxylamine, primary amines are obtained, with generally good yields and regioselectivity: J. Org. Chem., 60, 1912 (1995).
        • {ALF} For a brief feature on the reagent, see: Synlett, 1179 (1999); review of synthetic applications of organozirconocene compounds: Tetrahedron, 52, 12853 (1996)
        • {ALD} Merck: 14,8396
          • 37342-97-5 HXYJ0000003360 Bis(cyclopentadienyl)zirconium chloride hydride 氢氯二茂锆

          化学属性

          TSCANo
          Mol. FormulaC10H11ClZr
          Mol. Weight257.87
          Appearance off-white pwdr.
          Stabilitylight sensitive, moisture sensitive
          Melting Point300°C
          Boiling Point41.5°C at 760 mmHg
          Danger-Level-
          pH-:-
          Redox-

          *以上化合物性质及应用等信息仅供参考