{SA}

1. Aldrichimica Acta 17 , 75, (1984)

{SA}

Beil. 4 ,IV,4331

{SA}

Fieser 16 ,351

{SA}

Aldrich MSDS 1 , 1732:A / Corp MSDS 1 (2), 3401:A / FT-IR 1 (2), 1145:A / FT-IR 2 (3), 4486:A / FT-NMR 1 (3), 742:A / NMR-Reference 2 (2), 1022:C / RegBook 1 (2), 3053:A / Structure Index 1 , 484:B:1

{ALF} Catalyst for transesterification under neutral conditions: Bull. Soc. Chim. Fr., 262 (1969).

{ALF} Reacts with alcohols, by exchange, to give tri-n-butylstannyl ethers. Those derived from 3-halo alcohols cyclize on heating to give substituted oxetanes: J. Organomet. Chem., 47, 337 (1973):

{ALF}

{ALF} Similarly, 4-halo alcohols give tetrahydrofurans: J. Organomet. Chem., 50, 121 (1973).

{ALF} Enol acetates are converted to tin enolates which can undergo Pd-catalyzed coupling with aryl bromides to give arylacetones: Chem. Lett., 939 (1982); J. Chem. Soc., Chem. Commun., 344 (1983), and with vinyl bromides to give ß-unsaturated ketones: Bull. Chem. Soc. Jpn., 57, 242 (1984).

{ALF} For a review of organotin alkoxides in organic synthesis, see: Synthesis, 56, (1969).