Potassium thiocyanate, solution 0,1 mol/l (0,1 N) 硫氰酸钾溶液，0.1mol/l(1N)

规格: solution 0,1 mol/l (0,1 N)
CAS: 333-20-0
产品编号: PO03751000
MDL: MFCD00011413
品牌: Scharlab
Chemical NamePotassium thiocyanate, 99%
Synonym Potassium rhodanide
Beilstein Registry Number3594799
PubChem Substance ID516872
CAS Number333-20-0
EC Number206-370-1
MDL NumberMFCD00011413
Merck Number14,7691
Chemical Name Translation硫氰酸钾
InChIKeyZNNZYHKDIALBAK-UHFFFAOYSA-M
Wiswesser Line NotationSHCN &-KA-
LabNetwork Molecule IDLN00195268
InChIInChI=1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 4,1,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 594 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   JAPMA8 Journal of the American Pharmaceutical Association, Scientific
   Edition.  (Washington, DC) V.29-49, 1940-60.  For publisher information, see
   JPMSAE.  Volume(issue)/page

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAPMA8 Journal of the American Pharmaceutical Association, Scientific
   Edition.  (Washington, DC) V.29-49, 1940-60.  For publisher information, see
   JPMSAE.  Volume(issue)/page/year: 29,152,1940

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 854 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   JAPMA8 Journal of the American Pharmaceutical Association, Scientific
   Edition.  (Washington, DC) V.29-49, 1940-60.  For publisher information, see
   JPMSAE.  Volume(issue)/page/year: 29,152,1940

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - domestic
DOSE                    : 1779 mg/kg
SEX/DURATION            : female 1-20 week(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - endocrine system
REFERENCE :
   RJARAV Rhodesian Journal of Agricultural Research.  (Salisbury, Rhodesia)
   V.1-17, 1963-79.  Volume(issue)/page/year: 14,67,1976

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
WGK Germany1
RTECSXL1925000
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
    Risk Statements
    • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
    • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
    • R52/53
      Storage condition Store at RT. Moisture & Light Sensitive 密封干燥避光保存。 充氩保存
      Hazard statements
      • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
      • H331 Toxic if inhaled 吸入中毒
      • H302 Harmful if swallowed 吞食有害
      • H312 Harmful in contact with skin 皮肤接触有害
      • H302+H312+H332
      • H332 Harmful if inhaled 吸入有害
        Signal word Warning
        Precautionary statements
        • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
        • P362+P364
        • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
        • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
        • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
        • P501 Dispose of contents/container to..… 处理内容物/容器.....
        • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
        • P301+P317
        • P304+P340
        • P273 Avoid release to the environment. 避免释放到环境中。
        • P330 Rinse mouth. 漱口
        • P302+P352
          Hazard Codes Xn Xn,Xi
        • 配制硫氰酸盐滴定液。检定三价铁、铜和银。尿液检验。钨显色剂。容量法测定钛的指示剂。致冷剂。照相增厚剂。
        • {ALD} Merck: 14,7691
        • {ALF} Reaction with primary amine hydrohalide salts provides a useful synthesis of N-substituted and N,N'-disubstituted thioureas: Synthesis, 1569 (2000).
        • {ALD} Merck: 14,7691
        • Beilstein: 3,IV,299
          • 333-20-0 PO03751000 Potassium thiocyanate, solution 0,1 mol/l (0,1 N) 硫氰酸钾溶液，0.1mol/l(1N)

          化学属性

          Mol. FormulaKSCN
          Mol. Weight97
          Density1.890
          TSCAYes
          SolubilitySoluble in water (208 mg/ml at 20 °C), acetone, and alcohol.
          Boiling Point500° dec.
          Melting Point173
          Stability对光、空气和湿度敏感
          Flash Point500°C

          *以上化合物性质及应用等信息仅供参考