Perchloric acid, solution in acetic acid 0,1 mol/l (0,1 N) 高氯酸溶液， 0,1 mol/l (0,1 N)

规格: solution in acetic acid 0,1 mol/l (0,1 N)
CAS: 7601-90-3
产品编号: AC17651000
MDL: MFCD00011325
品牌: Scharlab
Chemical NamePerchloric acid
Synonym Fraude's reagent Hydrogen perchlorate PCA PERCHL PERCHLORIC ACID PERCHLORIC ACID 60% A.C.S. PERCHLORIC ACID 60 %, R. G., REAG. ISO PERCHLORIC ACID 60%, ACS, PACKED IN COAT ED GLASS BOTTLE PERCHLORIC ACID 70% PERCHLORIC ACID 70% (HG <0.0000005%), AC S PERCHLORIC ACID 70%, FOR TRACE ANALYSIS PERCHLORIC ACID STD SOL. IN 1,4-DIOXANE, 0.1 MOL/L, N20, 1 L PERCHLORIC ACID STD SOL. IN ACETIC ACID 0.1 MOL/L, N21, 1 L PERCHLORIC ACID STD. SOLUTION 0.001 MOL PERCHLORIC ACID, 70%, REDISTILLED, 99.99 9% PERCHLORIC ACID, VOLUMETRIC STANDARD, 0. 1N SOLUTION IN HOAC PERCHLORIC ACID-ACETIC ACID Perchloric Acid Perchloric acid Perchloric acid 70% Perchloric acid c Perchloric acid solution
CAS Number7601-90-3
PubChem Substance ID24247
MDL NumberMFCD00011325
EC Number231-791-2
Merck Number14,7153
Beilstein Registry Number2384789
Chemical Name Translation高氯酸
InChIInChI=1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 17(8),33,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1100 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 17(8),33,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 17(8),33,1973

WGK Germany1
Hazard Codes 5.1 O,C 8 O;C C,O,Xi Xi C
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H271 May cause fire or explosion; strong oxidizer 可能会引起火宅或爆炸；强氧化剂。
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
    Personal Protective Equipment Faceshields, Gloves, Goggles Eyeshields, Gloves Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSSC7500000
    Precautionary statements
    • P203
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
    • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
    • P234 Keep only in original container. 只保留在原来的容器中。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P264+P265
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P283 Wear fire/flame resistant/retardant clothing. 穿防火/阻燃/耐阻燃服。
    • P301+P312
    • P301+P312+P330
    • P301+P317
    • P301+P330+P331
    • P302+P361+P354
    • P303+P361+P353
    • P304+P340
    • P304+P340+P310
    • P305+P351+P338
    • P305+P354+P338
    • P306+P360
    • P308+P316
    • P309+P311
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P316
    • P317
    • P318
    • P319
    • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
    • P330 Rinse mouth. 漱口
    • P337+P313
    • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
    • P370+P378
    • P371+P380+P375
    • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
    • P403+P233
    • P403+P235
    • P404 Store in a closed container. 贮存于密闭容器中。
    • P405 Store locked up. 上锁保管。
    • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
    • P420 Store away from other materials. 远离其他材料。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger Warning
      Safety Statements
      • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S17 Keep away from combustible material 远离可燃物料；
        UN Number UN1873 UN 2920 8/PG 2 2920 UN1802 UN2920
        Risk Statements
        • R5 Heating may cause an explosion 加热会引起爆炸
        • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
        • R35 Causes severe burns 会导致严重灼伤
        • R10 Flammable 易燃
        • R34 Causes burns 会导致灼伤
        • R22 Harmful if swallowed 吞咽有害
        • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
          Packing GroupII
          Storage condition 密封保存。 Flammables area
          Hazard Class8
          Restrict 易制毒化学品
          Warnings 危化品目录(2015)
        • 分析上用作氧化剂及从钠中分离钾，分析铁合金中磷、铬、铁和硅，钾的定量，溶解金属。
        • {uni_hamburg} Short: II/25A
        • {uni_hamburg} Short: III/35E
        • {ALD} Merck: 14,7153
          • 7601-90-3 AC17651000 Perchloric acid, solution in acetic acid 0,1 mol/l (0,1 N) 高氯酸溶液， 0,1 mol/l (0,1 N)

          化学属性

          Mol. FormulaHClO4
          Mol. Weight100.46
          Density1.664
          Melting Point-122°C
          TSCAYes
          Refractive index1.4180
          Boiling Point130°C
          Vapor Pressure6.8 mmHg ( 25 °C)
          Vapor Density~2.1 (vs air)
          Flash Point113°(235°F)
          Stability对湿度敏感
          Solubility与水混溶。

          *以上化合物性质及应用等信息仅供参考