Ammonium thiocyanate, solution 0,1 mol/l (0,1 N) 硫氰酸铵溶液，0,1 mol/l (0,1 N)

规格: solution 0,1 mol/l (0,1 N)
CAS: 1762-95-4
产品编号: AM04201000
MDL: MFCD00011428
品牌: Scharlab
Chemical NameAmmonium thiocyanate
Synonym Ammonium thiocyanate {LY} Ammonium thiocyanate ammonium rhodanate ammonium thiocyanate ammonium thiocyanate, (15)N-labeled cpd thiocyanic acid thiocyanic acid, ammonium salt thiocyanic acid, barium salt thiocyanic acid, magnesium salt {} {LY} Ammonium thiocyanate {} {} {LY} Ammonium thiocyanate {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {}
CAS Number1762-95-4
PubChem Substance ID15666
EC Number217-175-6
Beilstein Registry Number3595135
MDL NumberMFCD00011428
Merck Number561
Chemical Name Translation硫氰酸铵
Wiswesser Line NotationSHCN &ZH
LabNetwork Molecule IDLN00193601
InChIInChI=1S/CHNS.H3N/c2-1-3;/h3H;1H3
Canonical SMILESN#CS.N
GHS Symbol
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 430 mg/kg
TOXIC EFFECTS :
   Behavioral - hallucinations, distorted perceptions
   Gastrointestinal - nausea or vomiting
   Gastrointestinal - other changes
REFERENCE :
   DAKMAJ Deutsches Archiv fuer Klinische Medizin.  (Leipzig, Ger. Dem. Rep.)
   V.1-211, 1865-1965.  For publisher information, see EJCIB8.
   Volume(issue)/page/year: 102,606,1911

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(10),51,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Former

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(10),51,1986

WGK Germany1
Hazard Codes
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H318 Causes serious eye damage 严重伤害眼睛
  • H332 Harmful if inhaled 吸入有害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
    Personal Protective Equipment Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Faceshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
    RTECSXK7875000
    Precautionary statements
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P264+P265
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312
    • P301+P312+P330
    • P301+P317
    • P301+P330+P331
    • P302+P352
    • P302+P352+P312+P362+P364
    • P304+P312
    • P304+P340
    • P304+P340+P312
    • P305+P351+P338
    • P305+P354+P338
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
    • P317
    • P319
    • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
    • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
    • P330 Rinse mouth. 漱口
    • P337+P313
    • P337+P317
    • P362+P364
    • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
    • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word
      Safety Statements
        Risk Statements
        • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
        • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
        • R52/53
          Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
          UN Number 9092
          Packing GroupIII
        • 用于形成新型二维 Cd-SCN 配位固体，该配位固体具有独特和可自行调节的方格状或人字形图案结构，这些结构对于获得科技实用性材料至关重要。
        • {ALD} Merck: 14,561
        • Beilstein: 3,IV,299
        • {ALF} In combination with CAN in t-butanol, epoxides are converted to thiiranes in high yield: Synthesis, 821 (1996). The same conversion can also be effected in the presence of SbCl3 in acetonitrile: Indian J. Chem., 38B, 605 (1999). CAN also promotes the direct conversion of activated aryl systems, e.g. indoles, pyrroles and N,N-dialkylanilines to aryl thiocyanates: Tetrahedron Lett., 40, 1195 (1999).
        • {uni_hamburg} Short: III/20a
        • {uni_hamburg} Short: III/20c
        • {ALF} Thiocyanogen bromide can be generated in situ by reaction with bromine in acetic acid, e.g. in the thiocyanation of N,N-dimethylaniline to 4-N,N-dimethylaminophenylisothiocyanate: Org. Synth. Coll., 2, 574 (1943).
        • {ALF} Also useful for the conversion of arylamines to thioureas either indirectly via benzoyl isothiocyanate: Org. Synth. Coll., 3, 735 (1955), or directly, but in lower yield, by reaction of ammonium thiocyanate with the amine in the presence of HCl: Org. Synth. Coll., 4, 180 (1963).
        • {ALD} Merck: 14,561
          • 1762-95-4 AM04201000 Ammonium thiocyanate, solution 0,1 mol/l (0,1 N) 硫氰酸铵溶液，0,1 mol/l (0,1 N)

          化学属性

          Mol. FormulaCH4N2S
          Mol. Weight76.12
          Melting Point152-154 °C
          Density1.3
          TSCAYes
          SolubilitySoluble in water, ethanol, methanol, ammonia, and acetone. Practically insoluble in CHCl3 and ethyl acetate.
          Flash Point190 ºC
          Stability对湿度、光和空气敏感
          Boiling Point262.85 °C at 760 mmHg

          *以上化合物性质及应用等信息仅供参考