Methylmagnesium bromide 甲基溴化镁

规格: 3.0 M solution in 2-Methyl-THF, SpcSeal
CAS: 75-16-1
产品编号: H11027
MDL: MFCD00000041
品牌: INFI
Chemical NameMethylmagnesium Bromide
MDL NumberMFCD00000041
CAS Number75-16-1
EC Number200-844-1
Beilstein Registry Number3535220
Reaxys-RN3909313
PubChem Substance ID87572429
Synonym Methyl magnesium bromide(in ethyl ether) methylmagnesium bromide sol. Methylmagnesium bromide, 1.4M solution in toluene/THF Methylmagnesium Bromide 2.0 M In n-Butyl Ether METHYLMAGNESIUM BROMIDE SOLUTION 甲基溴化镁 methyl-magnesiubromide(ethylethersolution)[qr] 甲基溴化镁, 3M乙醚溶液 溴甲基镁 Methylmagnesium bromide, 3M solution in diethyl ether 格利雅溶液 Methylmagnesium Bromide 1.0 M In Butyl Diglyme 甲基镁化溴 甲基溴鎂 Methylmagnesium Bromide 2.0 M In Tetrahydrofuran/Toluene 甲基溴化镁 溶液 Methylmagnesium Bromide 3.0 M In Diethyl Ether bromomethyl-magnesiu BROMOME 甲基溴化镁, 3M IN ETHER, PACKAGED UNDER ARGON IN RESEALABL METHYLMAGNESIUM BROMIDE, 3
Chemical Name Translation甲基溴化镁
LabNetwork Molecule IDLN00220157
InChIInChI=1S/CH3.BrH.Mg/h1H3;1H;/q-1;;+2/p-1
GHS Symbol
Signal word Danger
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R34 Causes burns 会导致灼伤
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P222 Do not allow contact with air. 不要与空气接触。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
      • P231+P232
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241+P242+P243
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P310
      • P301+P330+P331+P310
      • P302+P352+P332+P313+P362+P364
      • P303+P361+P353+P310+P363
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P310
      • P305+P351+P338+P337+P313
      • P308+P311
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
      • P332+P313
      • P335+P334
      • P337+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P370+P378
      • P402+P404
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P422 Store contents under… 存储目录在…之下。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        UN Number 3399
        Hazard statements
        • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
        • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
        • H302 Harmful if swallowed 吞食有害
        • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
        • H351 Suspected of causing cancer 怀疑致癌
        • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
        • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
        • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupII
          Storage condition water-free area Air & Moisture Sensitive 充氩保存
          Hazard Codes 4.3 F,C
          Hazard Class4.3/3
          RTECSOM3700000
          Warnings 危化品目录(2015)
          Restrict 危险品
        • ⑴.常温差压下为固体。与水接触有剧烈反应。对水、光和空气敏感。
        • ⑵. 吸入、摄入或经皮肤吸收后对身体有害。对眼睛、皮肤、 粘膜、和上呼吸道有强烈的刺激作用。接触后可引起咳嗽、肺炎、肺水肿等。同时还具有麻醉作用。
        • ⑶. 可与水、氧化物、酸、碱、醇反应。
        • Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
          • 75-16-1 H11027 Methylmagnesium bromide 甲基溴化镁

          化学属性

          Mol. FormulaCH3MgBr
          Mol. Weight119.24
          Density1.11
          Boiling Point78-80
          Flash Point-40°(-40°F)
          TSCAYes
          Stability对空气和湿度敏感
          Appearance brown liq. liq.
          RedoxReduction
          Danger-Level-
          pH-:-

          *以上化合物性质及应用等信息仅供参考