Diisobutylaluminum hydride 二异丁基氢化铝

规格: 1.5 M solution in toluene, SpcSeal
CAS: 1191-15-7
产品编号: H13013
MDL: MFCD00008928
品牌: INFI
Chemical NameDiisobutylaluminum hydride
CAS Number1191-15-7
EC Number214-729-9
Beilstein Registry Number4123663
MDL NumberMFCD00008928
Synonym 氫化二異丁基鋁 DIBAL-H Al-Alchili 二异丁基氢化铝, 25%甲苯溶液 Aluminum, diisobutylhydro- DIISOBUTYLALUMINUM HYDRIDE Bis(isobutyl)hydroaluminum 二异丁基氢化铝, 20% (CA 1M) SOLN. IN TOLUENE 氢化二异丁基铝 hydrobis(2-methylpropyl)-aluminu hydrobis(2-methylpropyl)-Aluminum DIBAL-H;DIBAL Aluminum, hydrodiisobutyl- DIISOBUTYLALUMINIUM HYDRIDE Aluminum, hydrobis(2-methylpropyl)- DIBAH 二异丁基氢化铝 溶液 Diisobutylhydroaluminum DIBAL-H DIBAL hydrobis(2-methylpropyl)aluminum 二异丁基氢化铝 DI-I-BUTYLALUMINUM HYDRIDE Diisobutylaluminum 二异丁基氢化铝, 1M SOLUTION IN HEXANE
PubChem Substance ID24852856
Chemical Name Translation二异丁基氢化铝
Wiswesser Line Notation1Y1&1-AL-H1Y1&1
GHS Symbol
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 70 gm/m3/1H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   MELAAD Medicina del Lavoro.  Industrial Medicine.  (Via S. Barnaba, 8, 20122
   Milan, Italy) V.16-    1925-  Volume(issue)/page/year: 57,188,1966

Signal word
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S29 Do not empty into drains 不要排入下水道;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R48/20
    • R17 Spontaneously flammable in air 在空气中能够自燃
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
    • R35 Causes severe burns 会导致严重灼伤
    • R34 Causes burns 会导致灼伤
    • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
    • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R37 Irritating to respiratory system 刺激呼吸道
    • R14 Reacts violently with water 遇水会猛烈反应
    • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
    • R51/53
      Precautionary statements
        Hazard statements
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
        • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
        • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
        • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H351 Suspected of causing cancer 怀疑致癌
        • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
        • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
        • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
        • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
        • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupI
          UN Number
          Storage condition Moisture Sensitive 易吸潮,密封充氩保存 Air & Moisture Sensitive 充氩保存 2-8°C
          RTECSBD0710000
          Hazard Codes F,C
          Hazard Class4.3
        • ⑴.无色液体,高度易燃。引起严重灼伤。吞食可能造成肺部损伤。蒸汽可能引起困倦和眩晕。
        • ⑵.主要用作精细化学品的还原剂和氢铝化剂。
        • ⑶.具有强烈的吸湿性,对空气和湿气敏感,遇水会发生激烈反应放出氢气。
        • ⑷.四氢呋喃不适宜作溶剂,因为两者反应生成配位化合物。二异丁基氢化铝是一种新型金属有机化合物,可使酮、羧酸、酯选择性还原成相应的醛或者醇。
        • Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.
        • {ALD} Merck: 14,10425
        • {ALF} Reduces chiral ɑ-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes: J. Chem. Soc., Chem. Commun., 2475 (1995).
        • {ALD} Merck: 14,10425
        • Beilstein:4(4)4400
        • 1191-15-7 H13013 Diisobutylaluminum hydride
二异丁基氢化铝

          化学属性

          Mol. Formula[(CH3)2CHCH2]2AlH
          Mol. Weight142.22
          Density0.848
          TSCAYes
          Flash Point-23°(-10°F)
          Boiling Point110
          Melting Point-70
          Solubility剧烈反应
          Stability易吸潮
          Density0.7051
          Mol. Formula[(CH3)2CHCH2]2AlH
          Mol. Weight142.22