Chemical Name | 3-Bromophenylboronic acid |
CAS Number | 89598-96-9 |
Alfabeta Name | BROMOPHENYLBORONICACID 3- |
MDL Number | MFCD00239386 |
Synonym |
3-Bromobenzeneboronic acid
3-Bromophenylboronic acid
3-溴苯硼酸 |
PubChem Substance ID | 87558907 |
Reaxys-RN | 3127104 |
Beilstein Registry Number | 3127104 |
EC Number | 000-000-0 |
Chemical Name Translation | 3-溴苯硼酸 |
Warnings |
IRRITANT, KEEP COLD |
WGK Germany | 3 |
Personal Protective Equipment |
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
Signal word |
Warning |
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
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Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
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Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S37 Wear suitable gloves 戴适当手套;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
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Risk Statements | |
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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GHS Symbol
{SA}
1. N. Uchiyama, et al., , Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution Chem. Commun. 47 , 11671-11673, (2011)
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2. A. Henke and J. Srogl, , Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids Chem. Commun. 47 , 4282-4284, (2011)
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3. T. Matsuda, et al., , Homocoupling of arylboronic acids catalyzed by simple gold salts Tetrahedron Lett. 52 , 4779-4781, (2011)
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4. F. Berhal, et al., , Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to a,ß-unsaturated ketones with DIFLUORPHOS and SYNPHOS analogues J. Org. Chem. 76 , 6320-6326, (2011)
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5. P. Tisovsky, et al., , Synthesis of aryl(ferrocenyl)methanols via an enantioselective addition of arylboronic acids Tetrahedron Asymmetry 22 , 536-540, (2011)
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6. H. Ihara, et al., , Anthranilamide: A Simple, Removable ortho-Directing Modifier for Arylboronic Acids Serving also as a Protecting Group in Cross-Coupling Reactions Org. Lett. 13 , 2662-2665, (2011)
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7. Y. Fujiwara, et al., , Practical C-H Functionalization of Quinones with Boronic Acids J. Am. Chem. Soc. 133 , 3292-3295, (2011)
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Org. Lett. 6 , 2205-2207, (2004) 摘要
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{SA} FT-IR 2 (3), 4463:D