3-Bromophenylboronic acid 3-溴苯硼酸

规格: 98%
CAS: 89598-96-9
产品编号: H20116
MDL: MFCD00239386
品牌: INFI
Chemical Name3-Bromophenylboronic acid
CAS Number89598-96-9
Alfabeta NameBROMOPHENYLBORONICACID 3-
MDL NumberMFCD00239386
Synonym 3-Bromobenzeneboronic acid 3-Bromophenylboronic acid 3-溴苯硼酸
PubChem Substance ID87558907
Reaxys-RN3127104
Beilstein Registry Number3127104
EC Number000-000-0
Chemical Name Translation3-溴苯硼酸
GHS Symbol
Warnings IRRITANT, KEEP COLD
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312
    • P302+P350
    • P302+P352
    • P302+P352+P332+P313+P362+P364
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P332+P313
    • P337+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S37 Wear suitable gloves 戴适当手套;
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • {SA}
        • 1. N. Uchiyama, et al., , Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution Chem. Commun. 47 , 11671-11673, (2011)
        • {SA}
        • 2. A. Henke and J. Srogl, , Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids Chem. Commun. 47 , 4282-4284, (2011)
        • {SA}
        • 3. T. Matsuda, et al., , Homocoupling of arylboronic acids catalyzed by simple gold salts Tetrahedron Lett. 52 , 4779-4781, (2011)
        • {SA}
        • 4. F. Berhal, et al., , Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to a,ß-unsaturated ketones with DIFLUORPHOS and SYNPHOS analogues J. Org. Chem. 76 , 6320-6326, (2011)
        • {SA}
        • 5. P. Tisovsky, et al., , Synthesis of aryl(ferrocenyl)methanols via an enantioselective addition of arylboronic acids Tetrahedron Asymmetry 22 , 536-540, (2011)
        • {SA}
        • 6. H. Ihara, et al., , Anthranilamide: A Simple, Removable ortho-Directing Modifier for Arylboronic Acids Serving also as a Protecting Group in Cross-Coupling Reactions Org. Lett. 13 , 2662-2665, (2011)
        • {SA}
        • 7. Y. Fujiwara, et al., , Practical C-H Functionalization of Quinones with Boronic Acids J. Am. Chem. Soc. 133 , 3292-3295, (2011)
        • {SA}
        • Org. Lett. 6 , 2205-2207, (2004) 摘要
        • {SA}
        • {SA} FT-IR 2 (3), 4463:D
        • 89598-96-9 H20116 3-Bromophenylboronic acid
3-溴苯硼酸

          化学属性

          Mol. FormulaC6
          Mol. Weight201
          Melting Point175-177
          TSCANo
          Density1.0

          *以上化合物性质及应用等信息仅供参考