Trichloroisocyanuric acid 三氯异氰脲酸

规格: 99%
CAS: 87-90-1
产品编号: H20591
MDL: MFCD00006553
品牌: INFI
Chemical NameTrichloroisocyanuric Acid
Synonym 1,3,5-TRICHLORO-2,4,6-TRIAZINETRIONE 1,3,5-Triazine, 2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- 1,3,5-Trichlor-1,3,5-triazin-2,4,6-trion 1,3,5-Trichlorhexahydro-1, 1,3,5-Trichloro-s-triazinetrione 1,3,5-trichloro-1,3,5-triazine-2,4,6(1H,3H,5H)-trione Fi Clor 91 Hi-Lite 90 Hi-Lite 90G Isocyanuric chloride Isocyanuric chloride, Symclosene Symclosen TCICA 三氯三嗪三酮 三氯 Trichlorocyanuric acid s-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- s-Triazine-2,4,6(1H,3H,5H)-trione, trichloro- trichloroisocyanuric acid {} {} {} {} {} {} {} {} {} {} {} {Chemi {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemi {} {} {} {} {} {} {} {} {Chemical {} {} {} {} {} {} {} {} {} {AL {} {} {} {} {} {} {} {}
CAS Number87-90-1
PubChem Substance ID6909
EC Number201-782-8
Beilstein Registry Number202022
MDL NumberMFCD00006553
Reaxys-RN202022
Merck Number9641
Chemical Name Translation三氯异氰尿酸
Wiswesser Line NotationT6NVNVNVJ AG CG EG
LabNetwork Molecule IDLN00194511
InChIInChI=1S/C3Cl3N3O3/c4-7-1(10)8(5)3(12)9(6)2(7)11
GHS Symbol
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1900 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
REFERENCE :
   MONS** Monsanto Co. Toxicity Information.  (Monsanto Industrial Chemicals
   Co., Bancroft Bldg., Suite 204, 3411 Silverside Rd., Wilmington, DE 19810)
   Volume(issue)/page/year: -,-,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 3570 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - ulceration or bleeding from stomach
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,167,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 406 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   42,417,1977

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2 gm/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MONS** Monsanto Co. Toxicity Information.  (Monsanto Industrial Chemicals
   Co., Bancroft Bldg., Suite 204, 3411 Silverside Rd., Wilmington, DE 19810)
   Volume(issue)/page/year: -,-,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 5010 mg/kg
TOXIC EFF

WGK Germany2
Hazard Codes 5.1 O,Xn,N O;Xn;N
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
    Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
    RTECSXZ1925000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
    • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P264+P265
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312
    • P301+P312+P330
    • P301+P317
    • P301+P330+P331
    • P302+P350
    • P302+P352
    • P302+P361+P354
    • P304+P312
    • P304+P340
    • P305+P351+P338
    • P305+P351+P338+P310
    • P305+P354+P338
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P316
    • P317
    • P319
    • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
    • P330 Rinse mouth. 漱口
    • P332+P313
    • P332+P317
    • P337+P313
    • P337+P317
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    • P362+P364
    • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
    • P370+P378
    • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
    • P403+P233
    • P405 Store locked up. 上锁保管。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      UN Number 2468
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S41 In case of fire and/or explosion do not breathe fumes 着火和/或爆炸时，不要吸入烟雾；
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
      • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
      • S8 Keep container dry 保持容器干燥；
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R31 Contact with acids liberates toxic gas 与酸接触释放出有毒气体
        • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
        • R50/53
        • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
          Storage condition Moisture Sensitive
          Packing GroupII
          Hazard Class5.1
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 该品具有极强的杀菌、漂白作用，广泛用于民用卫生，畜牧养殖业以及植保等作高效杀菌消毒剂，棉、麻化纤织物的洗涤漂白剂，羊毛防缩剂，也可用于橡胶氯化，电池材料，有机合成工业以及衣物的干法漂白等。
        • {ALFA} Note: Confusion with Cyanuric chloride, L03442, exists in some earlier Fieser references.
        • {ALFA} Low-cost chlorinating and oxidizing agent; review: Org. Process Res. Dev., 6, 384 (2002). Aromatic compounds can be chlorinated either on the ring (ionic conditions) or on the side chain (free-radical conditions): J. Org. Chem., 35, 719 (1970). In the presence of BF3 etherate, ketones are ɑ-chlorinated at the more substituted position: Synth. Commun., 15, 385 (1985). In combination with pyridine, sulfides are selectively oxidized to sulfoxides: Synth. Commun., 31, 245 (2001), thiols to disulfides: Synth. Commun, 31, 1825 (2001), and secondary alcohols to ketones: Synth. Commun., 22, 1589 (1992). In the presence of methanol in acetonitrile, acetone or dichloromethane, the same reagent system converts aldehydes directly to methyl esters: Synth. Commun., 26, 2633 (1996). Effective co-oxidant for the TEMPO-catalyzed chemoselective oxidation of alcohols to aldehydes and ketones: Org. Lett., 3, 3041 (2001). In acetic acid, pyridines are converted to their N-oxides: Synth. Commun., 34, 247 (2004).
        • {ALD} Merck: 14,9641
        • Beilstein:26,256
        • {uni_hamburg} Short: III/31a
        • {ALFA} With NaNO2 and wet silica selective mononitration of phenols is accomplished under mild conditions: Synlett, 191 (2003). Effectively catalyzes both the protection and deprotection of alcohols as their tetrahydropyranyl ethers: Synth. Commun., 34, 3623 (2004).
        • {ALFA} For a brief feature on uses in synthesis, see: Synlett, 2265 (2005).
        • {ALD} Merck: 14,9641
          • 87-90-1 H20591 Trichloroisocyanuric acid 三氯异氰脲酸

          化学属性

          Mol. FormulaC3Cl3N3O3
          Mol. Weight232.0
          Melting Point249 - 251 °C(lit.)
          Density2.19
          Flash Point>250°(482°F)
          TSCAYes
          Solubility1.2 G/100ML (25 ºC)
          Stability对湿度敏感

          *以上化合物性质及应用等信息仅供参考