Chemical Name | 1-Chloro-4-Fluorobenzene |
CAS Number | 352-33-0 |
Alfabeta Name | CHLOROFLUOROBENZENE 14--- |
MDL Number | MFCD00000603 |
PubChem Substance ID | 9604 |
EC Number | 206-521-1 |
Beilstein Registry Number | 1904542 |
Reaxys-RN | 1904542 |
Synonym |
{uni_hamburg}
1-chloro-4-fluorobenzene solution
4-Fluorochlorobenzene
p-Monofluoromonochlorobenzene
4-Fluorophenyl chloride
4-chlorofluorobenzene
4-CHLOROFLUOROBENZENE
1,4-Fluorochlorobenzene
p-Fluorochlorobenzene
4-CHLOROFLUOROBENZENE 99% (GC)
4-FLUOROCHLOROBENZENE
對氯氟苯
4-Chlorofluorobenzene
1-Chloro-4-fluorobenzene,98%
p-Monofluoromonochlorobenzene
1-Chloro-4-fluorobenzene
4-氯氟苯
4-Chlor-fluorbenzol
1-chloro-4-fluoro-benzen
4-氯氟苯;4-氟氯苯;对氯氟苯;对氟氯苯
1-chloro-4-fluoro-benzene
P-CHLOROFLUOROBENZENE
Benzene, 1-chloro-4-fluoro-
对氟氯苯
1-CHLORO-4-FLUOROBENZENE, 1000MG, NEAT
4-氟氯苯
1-Chloro-4-fluorobenzene99%
1-氯-4-氟苯
1-氯-4-氟苯,98%
4-Chlorfluorbenzol
p-Chlorofluorobenzene
对氯氟苯
4-Fluorchlorbenzol
P-FLUOROCHLOROBENZENE
1-Fluoro-4-chlorobenzene
1-CHLORO-4-FLUOROBENZENE, 1X1ML, MEOH, 5 000UG/ML |
Chemical Name Translation | 1-氯-4-氟苯 |
InChIKey | RJCGZNCCVKIBHO-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00225279 |
InChI | InChI=1S/C6H4ClF/c7-5-1-3-6(8)4-2-5/h1-4H |
Warnings |
危化品目录(2015)
IRRITANT, FLAMMABLE |
GHS Symbol
WGK Germany | 3 |
Hazard Codes |
3 |
Hazard statements | |
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H370 Causes damage to organs 导致器官损伤
- H331 Toxic if inhaled 吸入中毒
- H311 Toxic in contact with skin 皮肤接触中毒
- H301 Toxic if swallowed 吞食有毒
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
|
Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Precautionary statements | |
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P303+P361+
- P303+P361+P353
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
Signal word |
Danger
Warning |
Safety Statements | |
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
|
Risk Statements | |
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
UN Number |
1993 |
Packing Group | III |
Hazard Class | 3 |
Storage condition |
Flammables area |
Restrict |
危险品 |
{uni_hamburg} Short: II/27B
{ALF} Lithiation with LDA occurs mainly ortho to F; subsequent carboxylation gives 5-chloro-2-fluorobenzoic acid in moderate yield: Tetrahedron Lett., 33, 7495 (1992). The selectivity is improved by the use of the superbasic combination of n-BuLi and KO-t-Bu, and the yield is increased to 86%: Tetrahedron Lett., 37, 6551 (1996).