9-Borabicyclo[3.3.1]nonane 9-硼双环[3.3.1]壬烷

规格: 0.5 M solution in THF, SpcSeal
CAS: 280-64-8
产品编号: H24421
MDL: MFCD00074742
品牌: INFI
Chemical Name9-Borabicyclo[3.3.1]nonane
CAS Number280-64-8
EC Number206-000-9
Beilstein Registry Number605509
MDL NumberMFCD00074742
Synonym 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
PubChem Substance ID6327450
Chemical Name Translation9-硼双环[3.3.1]壬烷
InChIKeyFEJUGLKDZJDVFY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222630
InChIInChI=1S/C8H14B/c1-3-7-5-2-6-8(4-1)9-7/h7-8H,1-6H2
Canonical SMILESC1(B2)CCCC2CCC1
IUPAC Name9-borabicyclo[3.3.1]nonane
  • 使用 9-BBN 对相应环状缩醛进行还原以鉴别对称二醇。
  • 选择性硼氢化还原试剂。
  • Reactant for:
  • • Linear SPPS synthesis of ubiquitin derivatives
  • • Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
  • • Intramolecular insertion of alkenes into palladium-nitrogen bonds
  • • Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
  • • Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids
  • {PUB} EPA Chemicals under the TSCA --- https://www.epa.gov/tsca-inventory ---
  • {PUB} PubChem --- 9-BBN: An Amino Acid Protecting Group for Functionalization of Amino Acid Side Chains in Organic Solvents --- https://pubmed.ncbi.nlm.nih.gov/11950334
  • {PUB} PubChem --- A Boronium Ion with Exceptional Electrophilicity --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3457922
  • {PUB} PubChem --- Addition reactions at the 16(17) double bond of 3-methoxy-13$alpha;-estra-1,3,5(10),16-tetraene*1 --- https://pubmed.ncbi.nlm.nih.gov/12628692
  • {PUB} PubChem --- Suzuki cross-couplings of alkyl tosylates that possess beta hydrogen atoms: synthetic and mechanistic studies --- https://pubmed.ncbi.nlm.nih.gov/12386889
  • {PUB} PubChem --- Total Synthesis of (+)‐Oocydin A: Application of the Suzuki–Miyaura Cross‐Coupling of 1,1‐Dichloro‐1‐alkenes with 9‐Alkyl 9‐BBN --- https://pubmed.ncbi.nlm.nih.gov/18399555
  • {PUB} Thieme Chemistry --- Brominolysis --- https://science-of-synthesis.thieme.com/app/text/?id=SD-006-00939
  • {PUB} Thieme Chemistry --- By Reaction with Boranes --- https://science-of-synthesis.thieme.com/app/text/?id=SD-031-01897
  • {PUB} Thieme Chemistry --- Cross Coupling of Trialkylboranes --- https://science-of-synthesis.thieme.com/app/text/?id=SD-006-00962
  • {PUB} Thieme Chemistry --- Cyclization of α,α-Bis(dialkylboryl)-ω-haloalkanes --- https://science-of-synthesis.thieme.com/app/text/?id=SD-006-00925
  • {PUB} Thieme Chemistry --- Homologation by Carbonylation --- https://science-of-synthesis.thieme.com/app/text/?id=SD-006-00923
  • {PUB} Thieme Chemistry --- Hydroboration of Alkynes --- https://science-of-synthesis.thieme.com/app/text/?id=SD-006-00913
  • {PUB} Thieme Chemistry --- Hydroboration of Functional Derivatives of Alkenes --- https://science-of-synthesis.thieme.com/app/text/?id=SD-006-00912
  • {PUB} Thieme Chemistry --- Preparation of Alkylborohydrides --- https://science-of-synthesis.thieme.com/app/text/?id=SD-006-00056
  • {PUB} Thieme Chemistry --- Reaction of Boranes with
  • 280-64-8 H24421 9-Borabicyclo[3.3.1]nonane
9-硼双环[3.3.1]壬烷

    化学属性

    Mol. FormulaC8H15B
    Mol. Weight122
    Density0.89
    Boiling Point68 - 70 °C
    Flash Point1 °F
    Solubility起反应
    TSCANo
    Stability对空气和水分敏感
    Danger-Level甲类
    pH:A

    *以上化合物性质及应用等信息仅供参考