Chemical Name | 4-Nitrophenylboronic Acid |
CAS Number | 24067-17-2 |
Alfabeta Name | NITROPHENYLBORONICACID 4- |
MDL Number | MFCD00161360 |
Synonym |
p-Nitrophenylboronic acid
4-硝基苯硼酸
p-nitro-benzeneboronic acid
4-硝基苯基硼酸
4-Nitrophenylboronic acid
4-Nitrobenzeneboronic acid p-Nitrophenylboronic acid p-nitro-benzeneboronic acid
4-Nitrobenzeneboronic acid |
PubChem Substance ID | 87559783 |
Reaxys-RN | 3530497 |
Beilstein Registry Number | 16(4)1670 |
EC Number | 250-023-7 |
Chemical Name Translation | 4-硝基苯基硼酸 |
LabNetwork Molecule ID | LN00009603 |
Warnings |
IRRITANT |
WGK Germany | 3 |
GHS Symbol
Hazard statements | |
- H302 Harmful if swallowed 吞食有害
|
Hazard Codes |
Xn |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Signal word |
Warning |
Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
Safety Statements | |
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
|
Risk Statements | |
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
{SA}
1. Tang, J-S.; et al. , Efficient palladium-catalyzed Suzuki-Miyaura cross-coupling of iodoethynes with arylboronic acids under aerobic conditions Synthesis 17 , 2789-2795, (2011)
{SA}
2. Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
{SA}
{SA} 3. Reus, C.; et al. , Synthesis of Bromo-, Boryl-, and Stannyl-Functionalized 1,2-Bis(trimethylsilyl)benzenes via Diels-Alder or C-H Activation Reactions J. Org. Chem. 7th ed., 77 , 3518-3523, (2012) 摘要
{SA}
{SA} 4. Dieudonne-Vatran, A.; Azoulay, M.; Florent, J-C. , A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation Org. Biomolecular Chem. 13th ed., 10 , 2683-2691, (2012)
{SA}
5. Gavade, S.; et al. , Cu(acac)2-catalyzed N-arylations of phenylurea with arylboronic acid Synth. Commun. 11th ed., 42 , 1704-1714, (2012)
{SA}
6. Wang, L.; et al. , An efficient copper-catalyzed one-pot synthesis of diaryl thioethers by coupling of arylboronic acids with potassium ethyl xanthogenate under mild conditions Synlett 20 , 3041-3045, (2011)
{SA}
7. Kim, J.; et al. , Copper-Mediated Sequential Cyanation of Aryl C-B and Arene C-H Bonds Using Ammonium Iodide and DMF J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012) 摘要
{SA}
{SA} 8. Zhang, J.; et al. , Copper-catalyzed arylation of indolin-2,3-ones with arylboronic acids Tetrahedron 48th ed., 67 , 9347-9351, (2011)
{SA}
9. Nishino, T.; et al. , Regioselective glycosylation of unprotected methyl hexopyranoside by transient masking with arylboronic acid Heterocycles 2nd ed., 84 , 1123-1140, (2012)
{SA}
10. Marhadour, S.; et al. , An efficient access to 2,3-diarylimidazo[1,2-a]pyridines via imid