3-Chloro-3-methyl-1-butyne 3-氯-3-甲基-1-丁炔

规格: 97%
CAS: 1111-97-3
产品编号: H32800
MDL: MFCD00190221
品牌: INFI
Chemical Name3-Chloro-3-methyl-1-butyne
Synonym 3-Chloro-3-methyl-1-butyne
CAS Number1111-97-3
EC Number214-188-9
Beilstein Registry Number2384789
MDL NumberMFCD00190221
PubChem Substance ID70679
Chemical Name Translation3-氯-3-甲基-1-丁炔
InChIKeyQSILYWCNPOLKPN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009995
InChIInChI=1S/C5H7Cl/c1-4-5(2,3)6/h1H,2-3H3
Canonical SMILESC#CC(C)(Cl)C
IUPAC Name3-chloro-3-methylbut-1-yne
  • {PUB} Crystallography Open Database (COD)|PubChem|The Cambridge Structural Database --- 1,6,6-Trimethyl-1H-chromeno[6,7-d]thiazol-2(6H)-one --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961216
  • {PUB} PubChem --- Benzofuro[3,2-f][1]benzopyrans: A new class of antitubercular agents --- https://pubmed.ncbi.nlm.nih.gov/16616504
  • {PUB} PubChem --- Synthesis and Cytotoxic Activity of Benzo[a]pyrano[3,2-h] and [2,3-i]xanthone Analogues of Psorospermine, Acronycine, and Benzo[a]acronycine --- https://pubmed.ncbi.nlm.nih.gov/16880654
  • {PUB} PubChem --- Synthesis and Cytotoxic Activity of Benzopyranoxanthone Analogues of Benzo[b]acronycine and Psorospermine. --- https://pubmed.ncbi.nlm.nih.gov/11411515
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  • {PUB} PubChem --- The Influence of Carbon-Carbon Multiple Bonds on the Solvolyses of Tertiary Alkyl Halides: a Grunwald-Winstein Analysis --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2635746
  • {PUB} PubChem|Springer Nature --- Design and synthesis of novel 2,2-dimethylchromene derivatives as potential antifungal agents --- https://pubmed.ncbi.nlm.nih.gov/35639225
  • {PUB} PubChem|Springer Nature --- Indole Prenylation in Alkaloid Synthesis --- https://pubmed.ncbi.nlm.nih.gov/21915778
  • {ALF} Reagent for an improved 2-step introduction of the 1,1-dimethylallyl (DMA) ester protecting group for carboxylic acids. Reaction with the acid in the presence of copper(I) iodide and cesium carbonate in DMF affords the 1,1-dimethylpropargyl ester. Hydrogenation with Pd/barium sulfate/quinoline affords the 1,1-dimethylallyl ester. The DMA group is resistant to nucleophilic attack, but readily cleaved under non-acidic conditions with Pd(0), which is an advantage compared with the tert-butyl ester in solid-phase peptide synthesis: Org. Lett., 7, 1473 (2005).
  • {uni_hamburg} Short: EINECS Title: EINECS (European Inventory of Existing Com
  • 1111-97-3 H32800 3-Chloro-3-methyl-1-butyne
3-氯-3-甲基-1-丁炔

    化学属性

    Mol. FormulaC5H7Cl
    Mol. Weight103
    Density0.913
    Refractive indexn20/D 1.418(lit.)
    Boiling Point73-75°C at 760 mmHg
    Melting Point-61°C
    Flash Point4°C
    TSCAYes

    *以上化合物性质及应用等信息仅供参考