Chemical Name | 2-Bromopropionic |
CAS Number | 598-72-1 |
EC Number | 209-947-6 |
Synonym |
(±)-2-溴丙酸
(+/-)-2-BROMOPROPIONIC ACID
(±)-2-Brompropionsäure
(±)-2-bromo-propionic acid
(±)-α-Bromopropanoic acid
2-BROMOPROPIONIC ACID, 1000MG,NEAT
2-BROMOPROPIONIC ACID, 1X1ML, MTBE 1000U G/ML
2-bromopropanoic acid
2-溴代丙酸
DL-2-Bromopropionic acid
DL-2-溴丙酸
Propionic acid, 2-bromo-
{} {} {} {} {} {} {uni_hamburg}
α-Brompropionsäure
α-溴丙酸 |
MDL Number | MFCD00004211 |
Beilstein Registry Number | 605451 |
Reaxys-RN | 605451 |
PubChem Substance ID | 87563651 |
Chemical Name Translation | 2-溴丙酸 |
InChIKey | MONMFXREYOKQTI-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00239242 |
Hazard statements | |
- H290 May be corrosive to metals 可能腐蚀金属。
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
|
Hazard Codes |
8
C
C,Xi,F |
GHS Symbol
WGK Germany | 3 |
Signal word |
Danger |
Safety Statements | |
- S20 When using do not eat or drink 使用时,不得进食,饮水;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
|
Risk Statements | |
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
|
Precautionary statements | |
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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RTECS | UA2451715 |
UN Number |
3261
3265 |
Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Packing Group | II |
Hazard Class | 8 |
Warnings |
危化品目录(2015) |
Restrict |
危险品 |
有机合成中间体,用于生产除草剂、草萘胺,合成医药中间体丙氨酸。
{ALF} For a simplified variant of the reaction, applicable to the synthesis of ɑ-unsubstituted cinnamic acids, see Chloroacetic acid, A11482.
{uni_hamburg} Short: III/35E
{uni_hamburg} Short: III/20b
{ALF} Reaction of ɑ-halo alkanoic acids with a dialkyl phosphite in the presence of NaH, followed by treatment of the resulting phosphonoacetate salt with an aldehyde (or cycloalkanone) provides a convenient one-pot alternative to the Knoevenagel or Horner-Wadsworth-Emmons reactions for the synthesis of a variety of substituted acrylic acids: J. Org. Chem., 46, 2514 (1981):
{ALD} Beilstein:2,254