Bis(cyclopentadienyl)hafnium dichloride 二氯二茂铪

规格: 98%
CAS: 12116-66-4
产品编号: H37148
MDL: MFCD00001438
品牌: INFI
Chemical NameBis(cyclopentadienyl)hafnium dichloride
Synonym Dichlordicyclopentadienylhafnium bis(η-cyclopentadienyl)hafnium chloride Bis(cyclopentadienyl)hafnium dichloride Hafnocendichlorid Dichlorobis(eta-cyclopentadienyl)hafnium Dicyclopentadienylhafnium dichloride Dichlorodi-pi-cyclopentadienylhafnium bis(η-cyclopentadienyl)-hafnium chloride Hafnium, dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)- Dichlorodicyclopentadienylhafnium Hafnium, dichlorobis(η(5)-2,4-cyclopentadien-1-yl)- 二(环戊二烯基)二氯化铪(IV) 二(环戊二烯基)二氯化铪(IV) 二氯二茂铪 双(环戊二烯)二氯化铪(IV) 二(环戊二烯基)二氯化铪 双(环戊二烯)二氯化铪 dichlorobis(η5-cyclopenta-2,4-dien-1-yl)hafnium 二氯二茂铪 Hafnocene dichloride Hafnium dicyclopentadiene dichloride Hafnium, dichlorobis(η5-2,4-cyclopentadien-1-yl)-
MDL NumberMFCD00001438
EC Number235-177-5
CAS Number12116-66-4
PubChem Substance ID87571272
Chemical Name Translation二氯二茂铪
Wiswesser Line NotationL50J 0-HF-GG- 0L50J
InChIKeyUHCOEQZUSAFLHQ-UHFFFAOYSA-L
LabNetwork Molecule IDLN01745958
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04787

Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P308+P311
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      WGK Germany3
      Signal word Warning
      RTECSMG4815000
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Safety Statements
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S20 When using do not eat or drink 使用时，不得进食，饮水；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
        Packing GroupIII
        UN Number UN3261
        Risk Statements
        • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R34 Causes burns 会导致灼伤
          Storage condition Air & Moisture Sensitive
          Hazard Codes Xn Xi
        • {uni_hamburg} Short: IV/20A
        • Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds
        • Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R.
        • Editor: Hall, K.R.
        • Source: Landolt-Börnstein, New Series
        • Volume: IV/20A
        • Year: 1999
        • Keyword: organic compounds; vapor pressure
        • ISBN: 3-540-64735-X
        • ISBN: 978-3-540-64735-5
        • Internet Resource: DOI:10.1007/b71086
        • RefComment: VIII, 373 pages.
        • {uni_hamburg} Short: EINECS
        • Title: EINECS (European Inventory of Existing Commercial Chemical Substances)
        • Source: Official Journal of the European Communities
        • Volume: C 146 A (15.06.1990)
        • Page: 1
        • Year: 1990
        • Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein
        • Publish_Date: 1990/06/15
          • 12116-66-4 H37148 Bis(cyclopentadienyl)hafnium dichloride 二氯二茂铪

          化学属性

          Mol. FormulaC10H10Cl2Hf
          Mol. Weight379.58
          Melting Point230-233 °C(lit.)
          TSCAYes
          Appearance off-white xtl.
          Stabilitymoisture sensitive
          Density1.0

          *以上化合物性质及应用等信息仅供参考