2-Bromothiazole 2-溴代噻唑

规格: 97%
CAS: 3034-53-5
产品编号: H40577
MDL: MFCD00005316
品牌: INFI
Chemical Name2-Bromothiazole
CAS Number3034-53-5
Alfabeta NameBROMOTHIAZOLE 2-
MDL NumberMFCD00005316
Synonym 2-Bromothiazole {LY} 2-Bromothiazole {} {LY} 2-Bromothiazole {} {} {LY} 2-Bromothiazole {} {} {} {LY} 2-Bromothiazole {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {L
EC Number221-229-4
Beilstein Registry Number105724
PubChem Substance ID76430
Chemical Name Translation2-溴噻唑
Reaxys-RN105724
InChIKeyRXNZFHIEDZEUQM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00004618
InChIInChI=1S/C3H2BrNS/c4-3-5-1-2-6-3/h1-2H
Canonical SMILESBrC1=NC=CS1
GHS Symbol
Warnings IRRITANT, FLAMMABLE
Signal word Warning
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P305+P351+P338
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P403+P235
        Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
        Storage condition -20°C {LY} -20°C 2-8°C <0°C <;0 {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
        Hazard statements
        • H227 Combustible liquid 可燃液体
          Hazard Codes Xi,F
          UN Number 1993
        • 用于 5- 和 7-氮杂吲哚 N-芳基化反应的芳基卤化物。参与铜催化的氰化反应生成 2-氰基噻唑.
        • {ALF} 2-Lithiothiazole can be obtained by direct lithiation of thiazole or, more conveniently, by exchange with 2-bromothiazole using n-BuLi: J. Org. Chem., 53, 1748 (1988). It behaves as a valuable formyl anion equivalent, and as such has been applied, mainly by Dondoni's group, in the syntheses of a variety of products; see, e.g.: Tetrahedron Lett., 34, 7319, 7323, 7327 (1993). See also 2-(Trimethyl&#x00AD;silyl)&#x00AD;thiazole, B21903. Reaction of 2-lithiothiazole with nitrones gives ɑ-aminoaldehydes: Tetrahedron Lett., 33, 4221 (1992); stereocontrolled addition to C-galacto-pyranosylnitrone has been used in syntheses of destomic acid, a component of the antibiotics destomycin and hygromycin, and of lincosamine, the sugar component of the anticancer antibiotic lincomycin: Synlett, 78 (1993). For applications of 2-lithiothiazole in the synthesis of the aza-sugar (+)-galactostsin, see: J. Org. Chem., 60, 4749 (1995). The Thiazole Aldehyde Synthesis has been reviewed by Dondoni: Synthesis, 1681 (1998).
        • {TRC} Voogd, C.E., et al.: Mutation Research, Genetic Toxicology Testing, 118, 153 (1983),
          • 3034-53-5 H40577 2-Bromothiazole 2-溴代噻唑

          化学属性

          Mol. FormulaC3H2BrNS
          Mol. Weight164.02
          Boiling Point171 ℃
          Density1.8
          Refractive index1.5910 to 1.5950
          Flash Point67°C
          TSCAYes
          Solubility不溶
          pH:A
          Melting Point36.5 - 42.5 ℃

          *以上化合物性质及应用等信息仅供参考