Tetramethyltin 四甲基锡

规格: 97%
CAS: 594-27-4
产品编号: H40936
MDL: MFCD00008278
品牌: INFI
Chemical NameTetramethyltin
Synonym {uni_hamburg} tetramethyl-stannane Stannane, tetramethyl- Tetramethylstannane tin, tetramethyl- Tetramethylstannane- TETRAMETHYLTIN tetramethyl-stannan TETRAMETHYLTIN, 99+% Zinntetramethyl Tetramethylcin 四甲基锡 (CH3)4Sn tatramethyl stannane stannane, tetramethyl- tetramethyl-ti TIN TETRAMETHYL tetramethyl stannane Tin, tetramethyl- Tetramethyl tin Tetramethyltin,98% Tetramethylzinn tetramethylstannane 四甲錫 四甲锡 TETRAMETHYLSTANNANE tetramethyltin TETRAMETHYLTIN(IV)
CAS Number594-27-4
PubChem Substance ID11661
EC Number209-833-6
Beilstein Registry Number4,631
MDL NumberMFCD00008278
Reaxys-RN3647887
Chemical Name Translation四甲基锡
Wiswesser Line Notation1-SN-1&1&1
LabNetwork Molecule IDLN02129244
MDL NumberMFCD00008278
CAS Number594-27-4
InChIInChI=1S/4CH3.Sn/h4*1H3;
GHS Symbol
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2550 mg/m3/10M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,FEB1942

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1245,1986

WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes T+,N T+;N
    RTECSWH8630000
    Precautionary statements
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P305+P351+P338
    • P304+P340+P310
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P403+P233
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P303+P361+P353
    • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      Signal word Danger Warning
      UN Number UN 3384 6.1/PG 1 UN1992 3384 UN3384
      Risk Statements
      • R11 Highly flammable 非常易燃
      • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
      • R50/53
      • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
      • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        Safety Statements
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
        • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
        • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
        • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
        • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
        • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
        • S20 When using do not eat or drink 使用时,不得进食,饮水;
        • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
        • S33 Take precautionary measures against static discharges 对静电采取预防措施;
        • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
        • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
        • S4 Keep away from living quarters 远离生活区;
        • S27/28
          Packing GroupI
          Hazard Class6.1/3
          Storage condition 2-8°C
        • {SA}
        • Beil. 4 ,IV,4307
        • {SA}
        • FT-IR 1 (2), 1143:B / FT-NMR 1 (3), 737:A
        • {uni_hamburg} Short: II/25C
        • Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms
        • Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
        • Editor: Kuchitsu, K.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/25C
        • Year: 2001
        • Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
        • ISBN: 3-540-66774-1
        • ISBN: 978-3-540-66774-2
        • Internet Resource: DOI:10.1007/b71431
        • RefComment: VIII, 481 pages. Hardcover
        • Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
        • {uni_hamburg} Short: III/35C4
        • Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
        • Author: Gupta, R.R.; Platzer, N.
        • Editor: Gupta, R.R.; Lechner, M.D.
        • Source: Landolt-Börnstein, New Series
        • Volume: III/35C4
        • Year: 2001
        • Keyword: Hydrogen 1; Nuclear Magnetic Resonance
        • ISBN: 3-540-41059-7
        • ISBN: 978-3-540-41059-1
        • Internet Resource: DOI:10.1007/b76570
        • RefComment: VII, 299 pages. With CD-ROM. Hardcover
        • Abstract: This volume provides a comprehen
        • 594-27-4 H40936 Tetramethyltin	四甲基锡

          化学属性

          Mol. FormulaC4H12Sn
          Mol. Weight178.85
          Refractive index1.4390 to 1.4430
          Boiling Point76°C
          Density1.291
          Melting Point-54°
          Flash Point-12°C(lit.)
          SolubilityInsoluble in water. Soluble in organic solvents
          TSCAYes
          Mol. FormulaC4H12Sn
          Mol. Weight178.83
          Density1.3149
          Flash Point9°F
          Appearance colorless liq.
          Boiling Point76-78°C
          Melting Point-54.8°C