Palladium(II) trifluoroacetate 三氟乙酸钯

规格: 98%
CAS: 42196-31-6
产品编号: H41066
MDL: MFCD00013204
品牌: INFI
Chemical NamePalladium(II) Trifluoroacetate
Synonym 2,7-DICHLORO-9-FLUORENONE, TECH., 90% PALLADIUM (II) TRIFLUOROACETATE 97+% PALLADIUM TRIFLUOROACETATE Palladium(II) trifluoroacetate, min. 97% Palladium(II)trifluoroacetate,min.97% Pd(TFA)2 Trifluoroacetic acid palladium(II) salt 三氟乙酸 钯(II) 盐
MDL NumberMFCD00013204
PubChem Substance ID2733347
CAS Number42196-31-6
Reaxys-RN15732764
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation三氟乙酸钯
LabNetwork Molecule IDLN00197814
InChIInChI=1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Hazard Codes Xi
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Signal word Warning
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Hygroscopic
        • {ALFA} Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allyl­palladium(II)­ chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)­phosphine, L13329, has been found to give superior results to Palladium(II)­ acetate, 10516, or Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760, as a Pd source in Heck, Stille and Suzuki coupling reactions carried out in supercritical CO2: Tetrahedron Lett., 40, 2221 (1999).
        • {SA} Kato, K.; Motodate, S. et al. Angew. Chem. Int. Ed. Engl. 48 , 3326, (2009)
        • {SA} 2. Science 316 , 1172, (2007) 摘要
        • {SA} Tetrahedron Lett. 25 , 4187, (1984)
        • {ALF} Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allyl­palladium(II)­ chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)­phosphine, L13329, has been found to give superior results to Palladium(II)­ acetate, 10516, or Tris(d
        • {SA} R'kyek, O.; Halland, N. et al. Chem. Eur. J. 16 , 9986, (2010)
          • 42196-31-6 H41066 Palladium(II) trifluoroacetate 三氟乙酸钯

          化学属性

          Mol. FormulaC4F6O4Pd
          Mol. Weight332
          Melting Point210
          TSCANo
          Density1.422
          RedoxReduction

          *以上化合物性质及应用等信息仅供参考