Chemical Name | 2,5-Dimethoxytetrahydrofuran |
Synonym |
Tetrahydro-2,5-dimethoxyfuran
{LY} Tetrahydro-2,5-dimethoxyfuran
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{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrahydro-2,5-di |
CAS Number | 696-59-3 |
PubChem Substance ID | 79098 |
EC Number | 211-797-1 |
Beilstein Registry Number | 104261 |
MDL Number | MFCD00005359 |
Reaxys-RN | 104261 |
Chemical Name Translation | 2,5-二甲氧基四氢呋喃 |
InChIKey | GFISDBXSWQMOND-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00195115 |
InChI | InChI=1S/C6H12O3/c1-7-5-3-4-6(8-2)9-5/h5-6H,3-4H2,1-2H3 |
Canonical SMILES | COC1CCC(OC)O1 |
GHS Symbol
WGK Germany | 1 |
Hazard Codes |
3
Xn |
Hazard statements | |
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H331 Toxic if inhaled 吸入中毒
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Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Precautionary statements | |
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P280P305+P351+P338
- P301+P312
- P302+P352
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P370+P378
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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Signal word |
Danger
Warning |
UN Number |
1993
UN3271 |
Risk Statements | |
- R10 Flammable 易燃
- R20 Harmful by inhalation 吸入有害
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
- R36 Irritating to eyes 刺激眼睛
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Safety Statements | |
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
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Storage condition |
2-8°C, stored under nitrogen
{LY} 2-8°C, stored under nitrogen
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Packing Group | III |
Hazard Class | 3 |
该品为抗胆碱药物阿托品硫酸盐的中间体。还用作照相坚膜剂。
{ALD} Beilstein: 17,V,5,4
{ALFA} Cyclic acetal and in situ source of succindialdehyde.
{ALF} N-substituted pyrroles have also been formed with sulfonamides and primary amides. P2O5 has been reported to give superior results in this type of reaction: Synth. Commun., 25, 1857 (1995).
{ALF} Reacts with primary amines in boiling acetic acid to give N-substituted pyrroles: Acta Chem. Scand., 6, 667, 867 (1952); J. Heterocycl. Chem., 27, 1805 (1990); Org. Synth. Coll., 5, 716 (1973). Conversion to 1,4-dichloro-1,4-dimethoxybutane with TMS chloride allows cyclization with Amberlyst. A-21 resin, avoiding acidic conditions: J. Org. Chem., 48, 3059 (1983). Chiral 1-substituted pyrrole derivatives have been prepared using amino acids: Tetrahedron: Asymmetry, 7, 1069 (1996):