Chemical Name | Methyl formate |
Synonym |
Ameisensäuremethylester
C2H4O2 (formic acid methyl ester)
Formiate de methyle
Formic acid methyl ester
HCOOCH3
Methanoic acid, methyl ester
Methyl formate
Methyl methanoate
Methyle (formiate de)
Methylester kyseliny mravenci
Methylformiaat
Methylformiat
Mravencan methylnaty
formiatedemethyle
formiatedemethyle(french)
methyle(formiatede)(french)
甲酸甲酯
甲酸甲酯, 97%, CONT. CA 3% METHANOL
蚁酸甲酯 |
CAS Number | 107-31-3 |
EC Number | 203-481-7 |
Beilstein Registry Number | 1734623 |
MDL Number | MFCD00003291 |
Reaxys-RN | 1734623 |
Merck Number | 6077 |
PubChem Substance ID | 7865 |
Chemical Name Translation | 甲酸甲酯 |
Wiswesser Line Notation | VHO1 |
LabNetwork Molecule ID | LN00163744 |
InChI | InChI=1S/C2H4O2/c1-4-2-3/h2H,1H3 |
GHS Symbol
WGK Germany | 1 |
Hazard Codes |
3
F+,Xn |
Hazard statements | |
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- H302+H332
|
Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US) |
RTECS | LQ8925000 |
Precautionary statements | |
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P303+P361+P353
- P305+P351+P338
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
Signal word |
Danger |
UN Number |
1243 |
Risk Statements | |
- R12 Extremely flammable 极端易燃
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
|
Safety Statements | |
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S24 Avoid contact with skin 避免皮肤接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S33 Take precautionary measures against static discharges 对静电采取预防措施;
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
|
Packing Group | I |
Storage condition |
0-10
Flammables area
密封2-8°C保存
0-10°C |
Hazard Class | 3 |
Warnings |
危化品目录(2015) |
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 1622 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73.
For publisher information, see IOHSA5. Volume(issue)/page/year: 41,31,1972
Restrict |
危险品 |
气相色谱标准物质,溶剂,有机合成,杀菌剂,杀虫剂,烟熏剂。
{ALD} Merck:14,6077
Beilstein: 2,IV,20
{uni_hamburg} Short: II/14a
{uni_hamburg} Short: II/19b
{ALD} Merck:14,6077
{ALF} Formylating agent; see Ethyl­ formate, A11113.