Diethylene glycol dimethyl ether 二乙二醇二甲醚

规格: 99.5%
CAS: 111-96-6
产品编号: H48113
MDL: MFCD00008503
品牌: INFI
Chemical NameDiethylene glycol dimethyl ether
CAS Number111-96-6
Synonym 1-Methoxy-2-(2-methoxyethoxy)ethane {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methoxy-2-(2-methoxyethoxy)ethane {} {} {} {} {} {} {}
EC Number203-924-4
Beilstein Registry Number1736101
MDL NumberMFCD00008503
Merck Number3165
PubChem Substance ID87563527
Reaxys-RN1736101
Chemical Name Translation二乙二醇二甲醚
LabNetwork Molecule IDLN00163256
Canonical SMILESCOCCOCCOC
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   TOVEFN Toksikologicheskii Vestnik.  (18-20 Vadkovskii per.  Moscow, 101479,
   Russia) History Unknown  Volume(issue)/page/year: (1),27,1996

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5400 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   TOVEFN Toksikologicheskii Vestnik.  (18-20 Vadkovskii per.  Moscow, 101479,
   Russia) History Unknown  Volume(issue)/page/year: (1),27,1996

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 1000 ppm/5D (Continuous)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB83-138198

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 250 ppm/165M
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB83-138198

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 1000 ppm/5D (Continuous)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB83-138198

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - maternal-fetal exchange
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   16(3),567,1991

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 5 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB86-135233

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 2500 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volum

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1100 ppm/6H
SEX/DURATION            : male 2 week(s) pre-

Signal word Danger
WGK Germany1
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
    Risk Statements
    • R10 Flammable 易燃
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R60 May impair fertility 可能降低生殖能力
    • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
      Precautionary statements
      • P201 Obtain special instructions before use. 使用前获取专门指示。
      • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241+P242+P243
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P303+P361+P353
      • P305+P351+P338
      • P308+P313
      • P370+P378
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        RTECSKN3339000
        Packing GroupIII
        UN Number 3271 UN3271
        Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
        Hazard statements
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes 3 T
          Hazard Class3
        • 本品为非质子极性溶剂，可用于极性有机反应，阴离子聚合、配位离子聚合反应的溶剂，可作还原烷基化和缩合等反应溶剂，还可作为格氏和类似合成的介质，也用作无污染清洗剂、萃取剂、稀释剂、医药助剂及树脂溶剂。
        • {uni_hamburg} Short: II/27B
        • {ALF} Aprotic solvent which has useful solvent power, e.g. for Sodium borohydride, 35788, and hence has been widely used for in situ generation of diborane and for many other hydride reactions. For use in the hydroboration of olefins with borane-triethylamine complex, see: Org. Synth. Coll., 7, 427 (1990).
        • {ALD} Merck:14,3165
        • Beilstein:1(4)2393
        • {uni_hamburg} Short: III/38A
        • {ALD} Merck:14,3165
          • 111-96-6 H48113 Diethylene glycol dimethyl ether 二乙二醇二甲醚

          化学属性

          Mol. FormulaC6H14O3
          Mol. Weight134.17
          Density0.943
          Refractive index1.4060 to 1.4090
          Flash Point134.6 °F
          TSCAYes
          Boiling Point162 °C(lit.)
          Melting Point−67 - −61 °C(lit.)
          Autoignition Point370 °F
          Vapor Density4.6 (vs air)
          Vapor Pressure3 mmHg ( 20 °C)
          Solubility与水、烃类混溶。
          Stability易吸潮

          *以上化合物性质及应用等信息仅供参考