Chemical Name | Palladium |
MDL Number | MFCD00011167 |
PubChem Substance ID | 23938 |
CAS Number | 7440-05-3 |
EC Number | 231-115-6 |
Reaxys-RN | 4937491 |
Merck Number | 6989 |
Beilstein Registry Number | 2384789 |
Synonym |
Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {} {} {} {}
{} {} {} {} {} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {} {} {} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {} {} {} {} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Water)
{} {} {} {} {} {} {} {} {} {} {LY} Palladium on activated carbon(10%)(wetted with ca. 55% Wat |
Chemical Name Translation | 钯 |
InChIKey | KDLHZDBZIXYQEI-UHFFFAOYSA-N |
InChI | InChI=1S/Pd |
Canonical SMILES | [Pd] |
WGK Germany | 3 |
Personal Protective Equipment |
Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
RTECS | RT3480500 |
Safety Statements | |
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
|
UN Number |
3178
UN1325 |
Risk Statements | |
- R11 Highly flammable 非常易燃
|
GHS Symbol
Hazard Codes |
4.1
F |
Hazard statements | |
- H228 Flammable solid 易燃固体
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
|
Precautionary statements | |
- P233 Keep container tightly closed. ?保持容器密闭。
|
Signal word |
Danger |
Packing Group | III |
Storage condition |
Store at room temperature
{LY} Store at room temperature
{} {LY} Store at room temperature
{} {} {LY} Store at room temperature
{} {} {} {LY} Store at room temperature
{} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
Restrict |
危险品 |
主要用于电子工业厚膜浆料、多层陶瓷电容器内外电极材料。
{ALF} A large number of examples of hydrogenation reactions can be found in Organic Syntheses, although some of the earlier procedures may be somewhat outdated. A selection of rather more recent examples employing palladium on carbon include:
{ALF} General-purpose hydrogenation catalyst suitable for a wide variety of applications. For a monograph, see: P. N. Rylander, Hydrogenation Methods, Academic Press, N.Y. (1985).
{ALFA} Hydrogenation catalyst, which may be preferred where deactivation by the reaction products is possible:
{ALF} Hydrogenation of alkene to alkane: Org. Synth. Coll., 5, 97 (1973). Reduction of nitro to amine: Org. Synth. Coll., 5, 829 (1973). Reductive alkylation of amines: Org. Synth. Coll., 5, 552 (1973). Reduction of azide to amine: Org. Synth. Coll., 5, 586 (1973). High-pressure reduction of furan rings tetrahydrofurans: Org. Synth. Coll., 6, 856 (1988).
{ALD} Merck: 14,6989
{ALFA} Used in low-pressure hydrogenolysis of N-benzylamines: Org. Synth. Coll., 7, 152 (1990). Reduction of oximes to amines: Org. Synth. Coll., 5, 376 (1973). Widely used along with hydrogen donors such as Ammonium formate, A10699, Sodium formate, A17813, Formic acid, A13285, Cyclohexene, A11359, or Hydrazine monohydrate, A14005, for catalytic transfer hydrogenation reactions. In combination with Sodium borohydride, 13432, promotes the reduction of nitro-compounds to amines, where borohydride alone is ineffective: Synthesis, 713 (1987).