Phenyllithium 苯基锂

规格: 1.0 M solution in ethyl ether, SpcSeal
CAS: 591-51-5
产品编号: H51519
MDL: MFCD00014254
品牌: INFI
Chemical NamePhenyllithium
MDL NumberMFCD00014254
CAS Number591-51-5
Synonym 苯基锂 PhLi 苯基锂 溶液
PubChem Substance ID637932
Beilstein Registry Number506502
EC Number205-575-3
Chemical Name Translation苯基锂
LabNetwork Molecule IDLN00222202
InChIKeyDBYQHFPBWKKZAT-UHFFFAOYSA-N
InChIInChI=1S/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;/q-1;+1
GHS Symbol
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S8 Keep container dry 保持容器干燥；
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
    Packing GroupI
    UN Number UN2924
    Risk Statements
    • R14 Reacts violently with water 遇水会猛烈反应
    • R22 Harmful if swallowed 吞咽有害
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R50/53
    • R17 Spontaneously flammable in air 在空气中能够自燃
    • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
    • R34 Causes burns 会导致灼伤
    • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
      Storage condition 密封充氩保存 Air & Moisture Sensitive
      WGK Germany3
      Precautionary statements
      • P222 Do not allow contact with air. 不要与空气接触。
      • P305+P351+P338
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P231 Handle under inert gas. 在惰性气体中操作。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
        • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
        • H319 Causes serious eye irritation 严重刺激眼睛
          Signal word
          Hazard Codes 4.2
        • {ALD} Beilstein:16(4)1696
          • 591-51-5 H51519 Phenyllithium 苯基锂

          化学属性

          Flash Point25°(77°F)
          TSCAYes
          Boiling Point140 -143
          Solubility剧烈反应
          Stability对空气和湿度敏感
          Density0.815
          Mol. FormulaC6H5Li
          Mol. Weight84.04

          *以上化合物性质及应用等信息仅供参考