研峰科技 Infinity Scientific

tert-Butyl peroxybenzoate 过氧化苯甲酸叔丁酯

规格: 98%

CAS: 614-45-9

产品编号: H53928

MDL: MFCD00008802

品牌: INFI

Chemical Name	Tert-Butyl Peroxybenzoate
Synonym	tert.-Buty T-BUTYL PEROXYBENZOATE tert-Butyl benzoyl peroxide perbutylz { Perbenzoesäure-tert.-butylester 过氧化苯甲酸第三丁酯 CP 02 {Chemical peroxyb Novox TC 5 Benzoyl tert-butyl peroxide {Chemica PERBENZOIC ACID TERT-BUTYL ESTER Esperox 10 过氧化 Perbenzoate de butyle tertiaire T-BUTYL PERBENZOATE esperox10 Trigonox C {Ch tert< Perbutyl Z t {hazard_c 过氧化苯甲酸叔丁酯 Interox TBPB-HA-M 1 TC 5 (vulcanizer) Lup 过苯甲酸叔丁酯 VAROX TBPB peroxybenzoic acid tert-butyl ester t-Butyl perbenzoate Peroxybenzoic acid, tert-butyl ester {uni CP 02 (catalyst) terc.Butylperbenzoan 过氧化苯甲酸特丁酯过氧化叔丁 butylperoxybenzoate 叔丁基过氧化苯甲酸酯叔丁基过苯甲酸酯, 过苯甲酸特丁酯 Peroxybenzoesäure-tert.-butylester {C tert-Butyl perbenzoate {Che {uni_h t-Butyl peroxy benzoate benzoyltert-butylperoxide tert-Butyl peroxy benzoate tert-Butyl perbenzoate TERT-BUTYL PERBENZOATE Peroxybenzoesä Benzenecarboperoxoic acid tert-butyl ester VAROX TBPB-50 Chaloxyd TBPB-HA-M 1 Benzenecarboperoxoic acid, 1,1-dimethylethyl ester Benzolcarboperoxosäure-1,1-dimethylethylester perbenzoatedebutyletertiaire 过氧化叔丁基苯甲酸酯过 perbenzoatedebutyle 引发剂CP-01 tert-Butyl perbenzoate; TBPB 过氧化叔丁基苯甲
CAS Number	614-45-9
PubChem Substance ID	11966
EC Number	210-382-2
Beilstein Registry Number	1342734
MDL Number	MFCD00008802
Chemical Name Translation	过氧化苯甲酸叔丁酯
Wiswesser Line Notation	1X1&1&OOVR
LabNetwork Molecule ID	LN00226654
InChI	InChI=1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 311 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   RARSAM Radiation Research, Supplement.  (New York, NY)  No.1-7, 1959-67.
   Discontinued.  Volume(issue)/page/year: 3,193,1963

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >57 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 10,55,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1012 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,30,1982

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >57 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 10,55,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 914 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - necrotic changes
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshche

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 67 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

WGK Germany	2
Hazard statements
H242 Heating may cause a fire 加热可能会引起火灾 H315 Causes skin irritation 会刺激皮肤 H317 May cause an allergic skin reaction 可能导致皮肤过敏 H332 Harmful if inhaled 吸入有害 H400 Verytoxictoaquaticlife 对水生生物毒性非常大。 H241 Heating may cause a fire or explosion 加热可能会引起火灾或爆炸 H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	E;Xi
RTECS	SD9450000
Precautionary statements
P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。 P410 Protect from sunlight. 防止阳光照射。 P273 Avoid release to the environment. 避免释放到环境中。 P420 Store away from other materials. 远离其他材料。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P410+P412 P305+P351+P338 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P234 Keep only in original container. 只保留在原来的容器中。 P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P411+P235 P370+P378
Signal word
UN Number	UN3103 UN 3103 5.2
Risk Statements
R38 Irritating to skin 刺激皮肤 R7 May cause fire 会导致起火 R2 Risk of explosion by shock, friction, fire or other sources of ignition 遇到震动、摩擦、火焰或者其它引燃物有爆炸危险 R50 Very toxic to aquatic organisms 对水生生物极毒 R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S17 Keep away from combustible material 远离可燃物料； S47 Keep at temperature not exceeding ... °C (to be specified by the manufacturer) 保持温度不超过……°C（由生产厂家指定）； S39 Wear eye/face protection 戴眼睛/面孔保护装置； S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置； S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S7 Keep container tightly closed 保存在严格密闭容器中；
Packing Group	II
Storage condition	储存温度,2-8°C 必须贮存在聚乙烯容器中，温度在10℃-30℃ 2-8°C
Hazard Class	5.2
Warnings	危化品目录(2015)
Restrict	危险品

该品可作不饱和聚酯树脂加热成型的固化引发剂，以及高压聚乙烯、聚苯乙烯、邻苯二甲酸二烯丙酯（DAP）等各种树脂的聚合催化剂。

{uni_hamburg} Short: III/35E

{ALF} Promotes Pd-catalyzed oxidative coupling of electron-rich aromatics with electron-deficient alkenes: Tetrahedron, 40, 2699 (1984).

{ALF} Promotes the free-radical addition of bisulfite to vinyltrimethylsilane, in an improved preparation of 2-(TMS)ethanesulfonyl chloride: Org. Synth., 75, 161 (1997).

{ALD} Beilstein: 9,IV,715

{uni_hamburg} Short: EINECS

{ALF} In the presence of CuBr, effects dehydrogenation of oxazolines and thioazolines to the aromatized systems: J. Org. Chem., 61, 8207 (1996).

{ALF} For free-radical allylic benzoyloxylation of cyclohexene, promoted by CuBr, and references for preparation of benzoyloxy derivatives of other classes of compound including hydrocarbons, esters, ethers, sulfides, amides, etc., see: Org. Synth. Coll., 5, 70 (1973). The reaction with alkenes is also efficiently promoted by a complex of Cu(OTf)2 with DBN or DBU: Tetrahedron Lett., 37, 8435 (1996). For a review of acyloxylation at carbon, see: Synthesis, 1 (1972).

{ALFA} For free-radical allylic benzoyloxylation of cyclohexene, promoted by CuBr, and references for preparation of benzoyloxy derivatives of other class

614-45-9 H53928 tert-Butyl peroxybenzoate
过氧化苯甲酸叔丁酯

化学属性

Mol. Formula	C11H14O3
Mol. Weight	194.23
Refractive index	n20/D 1.499(lit.)
Boiling Point	75-76
Density	1.021
Flash Point	93°(199°F)
TSCA	Yes
Melting Point	8°C
Vapor Density	6.7 (vs air)
Vapor Pressure	3.36 mmHg ( 50 °C)
Solubility	不溶

*以上化合物性质及应用等信息仅供参考