4-Fluorophenylboronic acid 4-氟苯硼酸

规格: 98%
CAS: 1765-93-1
产品编号: H54682
MDL: MFCD00039136
品牌: INFI
Chemical Name4-Fluorobenzeneboronic acid
CAS Number1765-93-1
Alfabeta NameFLUOROPHENYLBORONICACID 4-
MDL NumberMFCD00039136
Synonym 4-Fluorobenzeneboronic acid {LY} 4-Fluorobenzeneboronic acid {} {LY} 4-Fluorobenzeneboronic acid {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzene
Beilstein Registry Number2829653
PubChem Substance ID285645
Reaxys-RN2829653
EC Number250-023-7
Chemical Name Translation4-氟苯硼酸
LabNetwork Molecule IDLN00008272
InChIInChI=1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
Canonical SMILESFC1=CC=C(B(O)O)C=C1
GHS Symbol
Warnings IRRITANT
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    WGK Germany3
    Signal word Warning
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
    • H302 Harmful if swallowed 吞食有害
    • H319 Causes serious eye irritation 严重刺激眼睛
      Hazard Codes Xn Xn,Xi Xi
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {
        • 用于四溴噻吩的Suzuki偶联反应中，也用于钯催化加腈。广泛用在和芳烃四氟硼酸重氮盐、碘盐的偶联反应，以及制造活性三联苯。
        • {SA} 8. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
        • {SA} 5. Inamoto, K.; et al. , Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones Chem. Commun. 36th ed., 48 , 4332-4334, (2012) 摘要
        • {SA} 7. Xue, F.; et al. , Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin-Sulfoxide Ligands J. Org. Chem. 7th ed., 77 , 3071-3081, (2012) 摘要
        • {SA} 6. Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
        • {ALD} Beilstein: 16,IV,1666
        • {ALF} For reactions of boronic acids, see Appendix 5.
        • {ALF} GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).
          • 1765-93-1 H54682 4-Fluorophenylboronic acid 4-氟苯硼酸

          化学属性

          Mol. FormulaC6H6BFO2
          Mol. Weight139.92
          Melting Point262-265°C
          TSCANo
          Density1.24
          Appearance white to off-white pwdr.
          Boiling Point258.4±42.0 °C at 760 mmHg

          *以上化合物性质及应用等信息仅供参考