Rhodium(II) acetate dimer 二聚醋酸铑

规格: 98%, 46% Rh
CAS: 15956-28-2
产品编号: H57636
MDL: MFCD00003538
品牌: INFI
Chemical NameRhodium(II) Acetate Dimer
Synonym Dirhodium tetraacetate {LY} Dirhodium tetraacetate {} {LY} Dirhodium tetraacetate {} {} {LY} Dirhodium tetraacetate {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium
MDL NumberMFCD00003538
PubChem Substance ID24852229
CAS Number15956-28-2
EC Number240-084-8
Reaxys-RN14201302
Beilstein Registry Number14201302
Chemical Name Translation乙酸铑(II)二聚体
Canonical SMILESO1=C([O-][Rh+2]234O=C([O-][Rh+2]14(O=C([O-]2)C)[O-]C(=O3)C)C)C
GHS Symbol
TYPE OF TEST            : LD10 - Lethal Dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 115 mg/kg
TOXIC EFFECTS :
   Tumorigenic - active as anti-cancer agent
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 20,943,1977

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSVI9361000
Hazard Codes Xi
Safety Statements
  • S15 Keep away from heat 远离热源；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
      Signal word Warning
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P305+P351+P338
        Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
      • 烯烃的环丙烷化，同源催化剂，高效催化剂，用于形成叶立德。
      • {ALF} Catalyst for various cyclization reactions involving ɑ-diazo carbonyl groups. Promotes the formation of macrocyclic lactones via intramolecular cyclopropanation and carbon-hydrogen insertion: J. Am. Chem. Soc., 117, 7181 (1995). For a brief feature on uses of the reagent in synthesis, see: Synlett, 3169 (2005).
      • {SA} Sugimura, T.; Mori, A. et. al. Tetrahedron Asymmetry 14 , 881, (2003)
      • {SA} Zhu, S.; Liao, Y.; Zhu, S. Org. Lett. 6 , 377, (2004) 摘要
      • {SA} Beil. 2 ,124
        • 15956-28-2 H57636 Rhodium(II) acetate dimer 二聚醋酸铑

        化学属性

        Mol. FormulaC8H12O8Rh2
        Mol. Weight441.99
        Melting Point205 °C
        TSCANo
        SolubilitySlightly soluble in ethanol
        Density1.422
        Appearance greenish-black xtl.

        *以上化合物性质及应用等信息仅供参考