Tetrabutylammonium iodide 四丁基碘化铵

规格: 99%
CAS: 311-28-4
产品编号: H58860
MDL: MFCD00011636
品牌: INFI
Chemical NameTetrabutylammonium iodide
Synonym Tetrabutylammonium (iodide) {LY} Tetrabutylammonium (iodide) {} {LY} Tetrabutylammonium (iodide) {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {}
CAS Number311-28-4
PubChem Substance ID67553
Beilstein Registry Number3916152
MDL NumberMFCD00011636
EC Number206-220-5
Reaxys-RN3916152
Chemical Name Translation四丁基碘化铵
InChIKeyDPKBAXPHAYBPRL-UHFFFAOYSA-M
Wiswesser Line Notation4K4&4&4 &I
LabNetwork Molecule IDLN00008641
InChIInChI=1S/C16H36N.HI/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
Canonical SMILESCCCC[N+](CCCC)(CCCC)CCCC.[I-]
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1990 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,489,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 69,327,1980

WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
    Hazard Codes Xn
    RTECSBS5450000
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312
    • P301+P312+P330
    • P302+P352
    • P304+P340
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
    • P330 Rinse mouth. 漱口
    • P332+P313
    • P337+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    • P403+P233
    • P405 Store locked up. 上锁保管。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R22 Harmful if swallowed 吞咽有害
          Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Light Sensitive & Hygroscopic {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
        • 离子对色谱试剂，相转移催化剂，极谱分析试剂。有机合成。
        • {ALF} Aliphatic and aromatic sulfonic acids are reduced to thiols in the presence of trifluoroacetic anhydride, followed by hydrolysis of the resulting trifluoroacetates: Tetrahedron Lett., 21, 1235 (1980).
        • {ALF} Catalyst for the high-yield methylation of alcohols with dimethyl sulfate: Angew. Chem., 85, 868; Angew. Chem. Int. Ed., 12, 846 (1973), or the benzylation of alcohols with benzyl bromide in organic solvents: Org. Synth. Coll., 8, 34 (1993); 9, 52 (1998).
        • {ALF} Useful source of I- for nucleophilic displacements, e.g. in the formation of neopentyl iodides from the triflates: J. Org. Chem., 45, 4387 (1980).
        • {uni_hamburg} Short: III/31a
        • {ALD} Beilstein:4(4)558
        • {ALF} In combination with Boron trifluoride diethyl­ etherate, A15275, has been used in a mild, versatile cleavage of ethers: Synthesis, 274 (1985).
          • 311-28-4 H58860 Tetrabutylammonium iodide 四丁基碘化铵

          化学属性

          Mol. FormulaC16H36IN
          Mol. Weight369.37
          Melting Point141-143°C
          TSCAYes
          Density1.2
          Stability对光敏感
          Solubilityacetonitrile: 0.1 g/mL, clear, colorless
          Boiling Point145.3 °C at 760 mmHg

          *以上化合物性质及应用等信息仅供参考